各种仪器分析的基本原理及谱图表示方法txt（The basic principle of instrument analysis and spectral representation method TXT）.docVIP

各种仪器分析的基本原理及谱图表示方法txt（The basic principle of instrument analysis and spectral representation method TXT） Spectral representation: post column effluent concentration changes with retention Information provided: the retention value of the peaks is related to the thermodynamic parameters of the components and is a qualitative basis. The peak area is related to the component content Reverse gas chromatography IGC Analysis principle: the change of the retention value of the probe molecule depends on the interaction between it and the polymer sample as the stationary phase Representation of the spectrum: the change of the numerical value of the probe molecule to the retention volume versus the column temperature Information provided: the relationship between the probe molecular retention value and temperature provides thermodynamic parameters of the polymer Pyrolysis gas chromatography PGC Analysis principle: the polymer material can be cracked instantaneously under certain conditions, and the fragments with certain characteristics can be obtained Spectral representation: post column effluent concentration changes with retention Information provided: the fingerprint or characteristic fragmentation peaks of the spectrum, characterizing the chemical structure and geometry of the polymer Gel chromatography GPC Analysis principle: when the sample passes through the gel column, the molecules are separated according to the mechanical fluid volume of the molecules, and the macromolecules flow out first Spectral representation: post column effluent concentration changes with retention Information provided: average molecular weight and distribution of polymers Thermogravimetry, TG Analysis principle: in a temperature controlled environment, the weight of a sample varies with temperature or time Spectral representation: the variation of the weight fraction of a sample with temperature or time The information is as follows: the curve drop is the sample weight loss area, and the plat