高氯酸氧化石墨.pdfVIP

Electrochimica Acta 116 (2014) 170–174 Contents lists available at ScienceDirect Electrochimica Acta j o u r n a l h o m e p a g e: w w w. elsev /locate/elec t a c ta Mildly expanded graphite for anode materials of lithium ion battery synthesized with perchloric acid Yuxiao Lin, Zheng-Hong Huang ∗ , Xiaoliang Yu, Wanci Shen, Yongping Zheng, Feiyu Kang Key Laboratory of Advanced Materials of Ministry of Education, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China a r t i c l e i n f o a b s t r a c t Article history: Mildly expanded graphite (MEG) was synthesized by using perchloric acid as both intercalating agent Received 29 September 2013 and oxidizing agent. Its performance as anode material for lithium ion battery was investigated. SEM, Received in revised form 9 November 2013 XRD, TEM, nitrogen adsorption and TGA/DSC were used to characterize the sample. Charge/discharge Accepted 9 November 2013 tests show that the MEG exhibits a rate capacity as high as 397 mAh/g at 0.2 C and 250 mAh/g at 1.6 C. Available online 20 November 2013 © 2013 Elsevier Ltd. All rights reserved. Keywords: Mildly expanded graphite Porous structure Lithium ion battery High capacity 1. Introduction high boiling point of sulfuric acid, resulting in some trouble in its