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【化学】高中化学22个易错知识点([chemical] high school chemistry 22 fallible points)
【化学】高中化学22个易错知识点([chemical] high school chemistry 22 fallible points)
1, hydroxyl is hydroxyl
It looks like a whole of OH. In fact, the hydroxyl group is a group. Its only a part of the material structure. It doesnt ionize. Which is a hydroxyl group of atoms, it is an anion, or strong or weak can ionize out. So, is not equal to the hydroxyl hydroxyl.
For example, the OH in C2H5OH is hydroxyl and will not ionize; two OH in sulfuric acid are also hydroxyl groups. As we all know, sulfuric acid can not ionize OH-. In NaOH, Mg (OH) 2, Fe (OH) 3, Cu2 (OH) 2CO3 in OH is the ion, ionization can come out, so here called hydroxyl.
2, Fe3+ ion is yellow
As we all know, FeCl3 solution is yellow, but does not mean that Fe3+ is yellow? No The alkali Fe (OH) 3 of Fe3+ is a weak base, and the salts synthesized by its binding with strong acid ions will hydrolyze to produce reddish brown Fe (OH) 3. Therefore, the concentrated FeCl3 solution is reddish brown, and the average concentration is yellow, which in the final analysis is caused by the hydrolysis of Fe (OH) 3. The real Fe3+ ion is mauve rather than yellow. Add Fe3+ solution to excess acid to inhibit hydrolysis, yellow will fade.
3, AgOH water decomposition
I find many people say so. In fact, the AgOH in the solubility table is -, which is considered to be water decomposition, but it is not. But the AgOH has a poor thermal stability and can be decomposed at room temperature, so the AgOH is decomposed immediately after metathesis, so that AgOH does not exist at room temperature. Water has nothing to do with it. If this operation is performed at low temperatures, the white precipitate of AgOH can be obtained.
4, polybasic oxygen acid, specific is a few yuan acid, see acid in the number of H.
What can the number of H+ polybasic ionization, is to see its structure in the number of hydroxyl groups, the hydroxyl hydrogen is not non ionizing out. Such as phosphite (H3PO3), it looks like there are three H, it seems to be three yuan aci
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