硅氢加成一步合成_氨基丙基三甲氧基硅烷.pdf

∀ 1028∀ PETRO CHEM ICA L TE CHN OLO GY 20 10 39 9 - 1 1 1 2 3 刘红艳 , 金 莉, 石万利 , 斯志惠, 吕连海 ( 1. , 1160 12; 2. , 116024; 3. , 115200) [ ] Speier, P t- N ( C H ) , 3 - 2 5 3 ( TM O S ) - ( KH - 540) , N 2 , n ( TM O S ) n ( 3 - ) = 1. 19 1( 3- 0. 064 m o ) Pt- N ( C H ) 1. 5 m o 0. 9 M Pa140 ! 2 5 3 270 m in, 3 - 87. 9% , KH - 540 81. 7% , [ ] - ; 3 - ; ; ; [ ] 1000- 8144 ( 20 10) 09 - 1028- 04 [ ] T Q 032. 4 [ ] A OneStep Synthesis of Am inopropyltrim ethoxysilane by Hydrosilylation 1 1 2 3 1 L iu H ongyan , J in L i , ShiW an i , Si Zh ihu i , L L ianha i ( 1. S tate K ey L aboratory of Fine C hem ica s, D a ian U n iversity of T echno ogy, D a ian L iaon ing 1160 12, Ch in a; 2. D a ian O n ichem C o. L td, D a ian L iaon ing 116024, C h ina; 3. G aizhou H engda Chem ica Products Co. L td, G aizhou L iaon in g 115200, C h ina) [Abstract] Am inopropy trmi e thoxy si ane ( KH540 ), u sed as si icane co up ing agent, w as synthesized by onestep hydrosiy a tion m ethod from 3am inopropene and trmi ethoxy si ane ( TM O S) w ith P ttr iethy am ine com p ex as cata y st w h ich w as prepared f rom Speier cata y st as precursor and N ( C H ) as ig and. Ef fects o f igand type, react ion tem per