cod常规测定方法（Cod routine determination method）.docVIP

cod常规测定方法（Cod routine determination method） COD routine determination method Two, potassium dichromate method to determine the principle of COD In strong acid solution, accurate adding potassium dichromate standard solution, excessive heating reflux, will be in water reducing substances (mainly organic oxidation), the excess potassium dichromate to ferroin indicator, with ferrous ammonium sulfate standard solution to drop, the COD calculated according to the amount of potassium dichromate standard solution. Cr2O72-+14H, ++6e, 2Cr3++7H2O (oxidation of water samples) Cr2O72-+14H, ++6Fe2+, 2Cr3++6Fe3++7H2O (titration) Fe2+ + test iron (indicator) - reddish brown (end point) Three, equipment 1. 250mL all glass reflux device; 2. quadruple adjustable furnace; 3.25 or 50ml acid burette, conical flask, pipette and volumetric flask etc.. Four reagents 1. potassium dichromate standard solution (C =0.2500mo1 / L): take the temperature of 2h in advance at 120 DEG C or high quality pure lead potassium 12.258g, dissolve in water, move into 1000mL capacity bottle, dilute to the mark, shake well. 2. test ferrous iron indicator: take 1.485g, phenanthroline (C12H8N2.H2O), 0.695g, ferrous sulfate FeSO4.7H2O) dissolved in water, diluted to 100ml, stored in a brown bottle. 3. ammonium ferrous sulfate standard solution (C = 0.1mol / L): 39.5g ammonium ferrous sulfate dissolved in water, stirring slowly add 20mL concentrated sulfuric acid, after cooling into 1000ml volumetric flask and diluted to shake line. Before use, calibrate with potassium dichromate standard solution. Calibration method: accurately absorb 10.00ml potassium dichromate standard solution in 500mL conical bottle, add dilution to 110ml or so, slowly add 30mL concentrated sulfuric acid, mix evenly. After cooling, add 3 drops of ferroin (about 0.15mL), which was titrated with ferrous ammonium sulfate solution, the solution color from yellow green to reddish brown with blue as the end point. In the formula, the concentratio