第六章. 生物氧化（The sixth chapter biological oxidation）.docVIP

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第六章. 生物氧化（The sixth chapter biological oxidation）.doc

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第六章. 生物氧化（The sixth chapter biological oxidation）

第六章. 生物氧化（The sixth chapter biological oxidation） The sixth chapter biological oxidation This chapter points The concept and characteristics of the biological oxidation: Oxidizing substances in organism decomposition and energy release process is called biological oxidation. And in vitro combustion, biological oxidation is a consuming O2, generation of CO2 and H2O, and the release of large amounts of energy. But in combustion is different, the bio oxidation process is at 37 degrees, nearly neutral aqueous environment, by enzyme catalytic reaction; gradually release energy, a considerable part of the energy stored in the form of high energy phosphate bond. Two, the type of high-energy phosphate bond: Bio chemical used in phosphate bond hydrolysis the energy released when 20kJ/mol called high-energy phosphate bond, mainly has the following several types: 1. acid anhydride 2. mixed anhydride bond 3. enol phosphate bond 4. guanidine phosphate bond Three, mitochondrial respiratory chain: The concept of 1. respiratory chain 2. respiratory chain The complex I (NADH- quinone reductase) Complex II (succinate ubiquinone reductase) Complex III Complex IV Four, the order of respiratory chain components: 1.NADH oxidation respiratory chain: the delivery of hydrogen or delivery of electron donor in the order: NAD+, [FMN (Fe-S)] - CoQ - B (Fe-S) - C1 - C - aa3 - 1/2O2. 2. succinate oxidation respiratory chain: the delivery of hydrogen or delivery of electron donor in the order: [FAD (Fe-S)] - CoQ - B (Fe-S) - C1 - C - aa3 - 1/2O2. Five, the organism energy generation way: 1. oxidativephosphorylation: The 2. substrate level phosphorylation: The six part, the coupling of oxidative phosphorylation: The number of moles of inorganic phosphorus consumption consumption per one mole of oxygen atoms called P/O ratio. When the substrate dehydrogenation with NAD+ as hydrogen acceptor, P/O ratio is about 3; and when the substrate dehydrogenation with FAD as hydrogen acceptor, P/O ratio is abou