镁合金微弧氧化化学镀镍层的界面结合.docVIP

论文题目: 镁合金微弧氧化/化学镀镍层的界面结合 专 业: 材料科学与工程 学 生: 签名 指导教师: 签名 摘 要 微弧氧化是在阳极氧化工艺基础上发展起来的一项新型表面处理技术，它是利用等离子体微区弧光放电现象在金属表面原位生长出一层陶瓷膜，以起到改善材料耐磨性、耐蚀性及绝缘性能的作用。同样，化学镀镍作为一种优良的表面处理技术，能够在形状复杂的铸件上得到厚度均匀的镀层，近年来得到广泛的重视和应用。本论文把微弧氧化技术及化学镀技术的优点结合起来，对镁合金进行微弧氧化—化学镀镍复合处理，制备了具有良好的复合涂层。 结果表明: 化学镀镍溶液中，Ni2+与H2PO2-浓度比为2.7化学镀的沉积速度最大，当Ni2+与H2PO2-浓度比为1:1时，镀层与基体的结合力最大。随着Ni2+与H2PO2-浓度比值的减小，镀层的非晶态结构越来越明显。溶液越偏碱性，镀层与基体的结合力就越小镀液H在7-8时，镀层与基体的结合力最大 关键词:镁合金; 微弧氧化; 化学镀镍 Title: The interface bonding strength of MAO/Ni–P composite coat on Mg alloy Major: Materials Science and Engineering Name: Signature： Supervisor: Signature： Abstract Micro-arc oxidation is a new type of surface treating technology on the basic of anode oxidation.It use plasma micro-arc to grow ceramic film on original position of metal surface,which can improve wear resistant，corrosion resistant and insulated character of material.As a kind of excellent surface treating technologies,electroless nickel plating can uniform coatings on complicated castings,which has been gained wide recognition and application in recent years.The paper get composite coatings with better interface bonding through electroless nickel plating combined with micro-arc oxidation treatment on magnesium alloy. The result shows: the rate of chemical deposition reach to maximum when the concentration ratio of Ni2+/H2PO2- in the electroless plating solution is about 1:2.7 and the binding force between matrix and coating reach to maximum when the concentration ratio of Ni2+/H2PO2- is 1:1 .With the reduce of the concentration ratio of Ni2+/H2PO2- ,the non crystalline structure of the coating become more and more obvious.The plating time should be limited between 40 min and 80 min in order to get better interface bonding.The influence of pH value is that the binding force between matrix and coating will become weak with th