碱金属盐改性炽热镁渣激冷水合脱硫剂-环境工程学报.PDF

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 碱金属盐改性炽热镁渣激冷水合脱硫剂 ∗ 侯宇,冯乐,李经宽,乔晓磊,金燕,樊保国 ￬ 太原理工大学电气与动力工程学院,太原 030024 摘　 要　 将炽热镁渣通过激冷水合以及碱金属盐添加剂改性的方法制得脱硫剂,并借助 TGA 研究改性脱硫剂钙转化率。 借助 XRD、SEM 和 BET 分析改性脱硫剂物质成分、表面形貌特征以及微观特征,从而获得炽热镁渣激冷水合过程中使用不 同碱金属盐改性添加剂的改性机理。 结果表明:对镁渣进行激冷水合和加入添加剂改性均可提高脱硫性能;NaCl 和 Na2 SO 的加入明显改善了脱硫剂的孔隙结构,Na CO 和 K CO 与镁渣水合产物发生化学反应生成 CaCO 并在改性脱硫剂表面 4 2 3 2 3 3 附着结晶;水合温度的升高有利于钙转化率的提高。 关键词　 炽热镁渣;激冷水合;碱金属盐;脱硫性能 中图分类号　 X511　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-2885-05　　 DOI　 10.12030/ j.cjee.201607238 Magnesium slag desulfurizer modified by alkali metal salt in quenching hydration HOU Yu,FENG Le,LI Jingkuan,QIAO Xiaolei,JIN Yan,FAN Baoguo∗ College of Electrical and Power Engineering,Taiyuan University of Technology,Taiyuan 030024,China Abstract　 In this paper,quenching magnesium slag desulfurizer was prepared in hydration and alkali metal salt additives used conditions. TGA was adopted for studying the calcium conversion rate. XRD,SEM and BET were adopted for analyzing the material composition,surface morphology and microscopic characteristics. The desulfu- rizer modification mechanism was obtained. The results show that quenching magnesium slag hydration process and additive modification can improve the desulfurization capability. NaCl and Na SO improve the pore structure2 4 of the desulfurization sorbent obviously,and Na CO and K CO react with the magnesium slag hydration prod- 2 3 2 3 ucts as CaCO which crystallizes on the surface of modified desulfurizer. When the hydration temperature is in- 3 creased,the calcium conversion rate is enhanced. Key words