聚乙烯醇明胶混合水溶液静电纺丝.pdf

Vol. 21 No. 3 312 Journal of Functional Polym ers 2008 9 1, 2 2 1 1 张春雪 , 崔龙辉 , 袁晓燕 , 盛 京 ( 1. 天津大学材料科学与工程学院, 天津300072; 2. 天津理工大学化学化工学院, 天津300191) : 将聚乙烯醇与明胶 合水溶液进行静电纺丝, 制备了聚乙烯醇与明胶 合超细纤维及 其电纺膜, 研究了 合纺丝液的组成对纺丝液的粘度表面张力和电导率的影响, 观察了纤维的微 观形貌, 并对电纺膜进行了差示扫描量热测定结果表明: 当 合液中明胶含量小于20% 时, 静电 纺丝可以稳定进行随着明胶含量由5% 逐渐增加至25%, 合超细纤维的平均直径先是由2 0 nm 逐渐下降至207 nm 而后又逐渐增加至320 nm明胶的含量低于15% 时, 不影响其 合电纺 膜中PVA 的结晶 : 静电纺丝; 聚乙烯醇; 明胶; 合 : O 3 : A : 1008-9357( 2008) 03-0312-05 Electrospinning of Poly(Vinyl Alcohol )/ Gelatin Aqueous Solution 1, 2 2 1 1 ZHANG Chun-xue , CU I Long-hui , YUAN Xiao-yan , SHENG Jing ( 1. School of M aterials Science and Engineering, Tianjin U niversity , T ianjin 300072, China; 2. School of Chemistry and Chemical Engineering, Tianjin University of Technology , Tianjin 300191, China) Abstract: Ultrafine fibers and fiber mats of poly( vinyl alcohol) w ith gelatin w ere prepared by electro- spinning in aqueous solution. Effects of the composition of the spinning solution on the properties such as viscosity, surface tension and conductivity w ere studied. The morphology of fibers w as observed, differen- tial scanning calorimetry w as also conducted. The results show that the electrospinning is stable w hen gelatin content is less than 20% . With gelatin content increased from 5% to 25% , the average diameter of fibers decreased from 2 0 nm to 207 nm at first, and then increased to 320 nm gradually. According to differential scanning calorimetry thermal analysis, addition of