《材料热力学》作业-论文翻译.docxVIP

《材料热力学》作业材料与能源学院材料工程xxx学号xxx文章来源：ElectrochimicaActa 214 (2016) 56-67A Combined Thermodynamics Computational Method to Assess Lithium Composition in Anode and Cathode of Lithium Ion Batteries锂离子电池正极与负极锂成分的热力学计算方法Wenyu Zhang, Lianlian Jiang, Pauline Van Durmen, SomayeSaadat, RachidYazamiEnergy Research lnstitute@NTU (ERIAN), Nanyang Technological University, 1 Cleantech Loop, CleanTech One, #06-04, Singapore 637141, SingaporeABSTRACTWith aim to address the open question of accurate determination of lithium composition in anode andcathode at a defined state of charge (SOC) of lithium ion batteries (LIB), we developed a methodcombining electrochemical thermodynamic measurements (ETM) and computational data fittingprotocol. It is a common knowledge that in a lithium ion battery the SOC of anode and cathodediffer fromthe SOC of the full-cell. Differences are in large part due to irreversible lithium losses within cell and to electrode mass unbalance. This implies that the lithium composition range in anode and in cathode during full charge and discharge cycle in full-cell is different from the composition range achieved in lithium half-cells of anode and cathode over their respective full SOC ranges. To the authors knowledge there is no unequivocal and practical method to determine the actual lithium composition of electrodes in a LIB, hence their SOC. Yet, accurate lithium composition assessment is fundamental not only for understanding the physics of electrodes but also for optimizing cell performances, particularly energy density and cycle life.摘要这个开放性的课题旨在解决在给定的锂离子电池（LIB）的充电状态（SOC）下准确测定阳极和阴极的锂化合物组成的。我们开发了一种电化学热力学测量（ETM）与计算数据拟合相结合的方法。众所周知，半锂离子电池中的阳极和阴极的与锂电池不同。这种差异在很大程度上是由于电池内不可逆的锂损失和电极质量的不平衡。这意味着，在电池的充放电循环期间，在阳极和阴极中的锂化合物的组成与半电池的阳极和阴极锂化合物的组成是不同的。据作者所知，还没有有效的方法来确定半电池的实际锂化合物的组成。然而，测量准确的锂电极的成分的对于了解电极的物理变化、优化电池的性能（特别是能量密度和循环寿命）是十分重要的。In this study thermodynamics data, including open-circuit potential (OCP), entropy (ΔS) and enthalpy (ΔH) are collected on full-cells and on