charge transfer properties in meh-ppvpsmwcnts nanocomposites电荷转移属性meh-ppvpsmwcnts纳米复合材料.pdfVIP
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charge transfer properties in meh-ppvpsmwcnts nanocomposites电荷转移属性meh-ppvpsmwcnts纳米复合材料
Journal of Surface Engineered Materials and Advanced Technology, 2012, 2, 174-181
/10.4236/jsemat.2012.23028 Published Online July 2012 (http://www.SciRP.org/journal/jsemat)
Charge Transfer Properties in MEH-PPV/PS:MWCNTs
Nanocomposites
1* 1 1 2 1
Nadia Chehata , Olfa Dhibi , Adnen Ltaief , Ali Farzi , Abdelaziz Bouazizi
1Equipe Composants Electroniques Organiques et Photovoltaïques Moléculaires, Département de Physique, Faculté des Sciences de
Monastir, Monastir, Tunisie; 2Department of Material and Polymer Engineering, Faculty of Engineering, Sabzevar Tarbiat Moallem
University, Sabzevar, Iran.
*
Email: nadiachehata2@
Received December 13th, 2011; revised January 15th, 2012; accepted January 28th, 2012
ABSTRACT
The effect of composition and annealing temperature on charge transfer properties, in a donor/acceptor nanocomposites
based on poly(2-methoxy-5-(2-ethyhexyl-oxy)-p-phenylenevinylene) (MEH-PPV) and MWCNTs functionalized with
Polystyrene (PS:MWCNTs), have been investigated. The quenching of photoluminescence (PL) intensity of pure
MEH-PPV, by adding different amounts of functionalized carbon nanotubes, exhibits that a photoinduced charge trans-
fer has been occurred. Charge transfer efficiency was obtained for an acceptable concentration of PS:MWCNTs about
0.5 wt% and at annealed temperature of about 80˚C. Quenching efficiency studies imply that MEH-PPV/PS:MWCNTs
nanocomposites reveal a high degree of PL quenching, reaching a value of η = 76.9%.
Keywords: Poly(2-methoxy-5-(2-ethyhexyl-oxy)-p-phenylenevinylene) (MEH-PPV); Functionalized Carbon
Nanotubes; Charge Transfer; Nanocomposites
1. Introduction applications. It seems that functionalization of CNTs
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