原创力文档comparative study on application of bimetallic pt-based alloy electrocatalysts in advanced chlor-alkali electrolysis比较研究上的应用在先进的双金属合金pt-based electrocatalysts氯碱电解.pdfVIP
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comparative study on application of bimetallic pt-based alloy electrocatalysts in advanced chlor-alkali electrolysis比较研究上的应用在先进的双金属合金pt-based electrocatalysts氯碱电解
Engineering, 2011, 3, 836-841
doi:10.4236/eng.2011.38102 Published Online August 2011 (http://www.SciRP.org/journal/eng)
Comparative Study on Application of Bimetallic
Pt-Based Alloy Electrocatalysts in Advanced
Chlor-Alkali Electrolysis
1* 1 2
Faezeh Farzami , Ezzatoalah Joudaki , Seyed Jaleldin Hashemi
1
Department of Chemical Engineering , University of Arak, Arak, Iran
2Petroleum University of Technology, Ahvaz, Iran
E-mail : Faezeh_farzami@
Received January 29, 2011; revised May 25, 2011; accepted June 10, 2011
Abstract
Application of an oxygen-depolarized cathode will contribute to energy saving in chlor-alkali electrolysis.
For this purpose, the development of high-performance cathode with the best electrocatalyst is essential. Us-
ing bimetallic Pt-based alloy electrocatalysts including PtPd and PtAg carbon-supported in oxygen-depolar-
ized cathode chlor-alkali cell has been shown to have the high cell performance. This study presents applica-
tion of PtRu carbon supported electrocatalyst oxygen-depolarized cathode and performance comparison of
cells with carbon-supported PtRu, PtPd and PtAg electrocatalysts cathodes using the same DSA-Cl2 anode.
Results show that there are quite similarity between the effects of various factors on the caustic current effi-
ciency (CCE) in a zero-gap oxygen-depolarized chlor-alkali cells employing carbon-supported PtPd, PtRu
and PtAg electrocatalysts. Besides, it seems that the PtPd/C electrocatalyst cathode has relatively higher
performance than the other cathodes with PtAg/C and PtRu/C electrocata
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