原创力文档eco-friendly synthesis of cyclododecanone from cyclododecatriene环保从环十二碳三烯合成cyclododecanone.pdfVIP
- 1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
- 2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击 这里二次下载。
- 3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
- 4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
- 5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
- 6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
- 7、VIP文档为合作方或网友上传，每下载1次， 网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档
查看更多
eco-friendly synthesis of cyclododecanone from cyclododecatriene环保从环十二碳三烯合成cyclododecanone
Green and Sustainable Chemistry , 2011, 1, 63-69
doi:10.4236/gsc.2011.13011 Published Online August 2011 (http://www.SciRP.org/journal/gsc)
Eco-friendly Synthesis of Cyclododecanone from
Cyclododecatriene
*
Qi Feng, De-Kai Yuan, Dao-Quan Wang, Xiao-Mei Liang , Jian-Jun Zhang, Jin-Ping Wu,
Fu-Heng Chen
Key Laboratory of Pesticide Chemistry and Application Technology, Department of Applied Chemistry,
China Agricultural University, Beijing, China
*
E-mail : liangxiaomeim@
Received June 21, 2011; revised July 23, 2011; accepted July 29, 2011
Abstract
An eco-friendly synthesis of cyclododecanone (CDON) from cyclododecatriene (CDT) is described. Selec-
tive epoxidation of CDT with hydrogen peroxide using hexadecyl trimethyl ammonium heteropolyphospha-
totungstate [(n-C H NMe ) PW O , HAHPT] as catalyst and water as solvent followed by the hydrogena-
16 33 3 3 4 16
tion on Raney nickel catalyst gave cyclododecanol (CDOL). The latter was oxidized with hydrogen peroxide
using HAHPT as catalyst and a mixture of water and t-butanol as solvent to afford CDON. The total yield
was 53.4% under the optimum reaction conditions.
Keywords: Eco-Friendly Synthesis, Cyclododecanone, Cyclododecatriene, Hexadecyl Trimethyl Ammonium
Heteropolyphosphatotungstate
1. Introduction 2. Experimental
Cyclododecanone (CDON) is an important precursor for 2.1. General
laurolactam which is required for the production of
Nylon-12 poss
您可能关注的文档
- duality of measure and category in infinite-dimensional separable hilbert space二元性无限维度的测量和类别可分离希尔伯特空间.pdf
- dufour and soret effect on steady mhd flow in presence of heat generation and magnetic field past an inclined stretching sheet杜福尔和俗影响稳定的磁流体动力流存在的热量生成和磁场过去一个斜拉伸板.pdf
- duality without constraint qualification in nonsmooth optimization在非光滑优化二元性约束资格.pdf
- dual solutions on thermosolutal marangoni forced convection boundary layer with suction and injection双重解决方案thermosolutal马朗戈尼强制对流边界层抽吸和注入.pdf
- duality models for some nonclassical problems in the calculus of variations一些模问题的对偶模型的变分法.pdf
- duals for classical inventory models via generalized geometric programming通过广义几何规划双刀经典库存模型.pdf
- dunkl translation and uncentered maximal operator on the real linedunkl翻译和偏心最大运营商在实线.pdf
- due-window assignment and scheduling with multiple rate-modifying activities under the effects of deterioration and learning与多个rate-modifying due-window分配和调度活动恶化和学习的影响.pdf
- duality property for positive weak dunford-pettis operators为积极的弱对偶性dunford-pettis运营商.pdf
- durability of tubular geopolymer reinforced with silica sand耐久性与硅砂管状地质聚合物的增强.pdf
- economic and social impact of tourism on a small town peterborough new hampshire经济和社会的影响旅游业在彼得伯勒新罕布什尔州的一个小镇.pdf
- eclecticism or principled eclecticism折衷主义和折衷主义原则.pdf
- economic dispatch with multiple fuel options using ccf经济调度与多个燃料使用ccf选项.pdf
- echogenic technology improves cannula visibility during ultrasound-guided internal jugular vein catheterization via a transverse approach反射波的技术改善插管能见度在超声引导下颈内静脉导管插入术通过横向的方法.pdf
- economic growth and a low carbon economy―does the earth suffer from an “easter island syndrome”经济增长和低碳经济真的地球受到u201c复活节岛综合症u201d.pdf
- economic growth and business cycles the labor supply decision with two types of technological progress经济增长和经济周期的劳动力供给决策两种类型的技术进步.pdf
- economic freedom and foreign direct investment how different are the mena countries from the eu经济自由和外国直接投资是欧盟的中东和北非地区的国家是多么的不同.pdf
- early postprandial insulin secretion its relation to insulin sensitivity早期的餐后胰岛素分泌胰岛素敏感性的关系.pdf
- economic impacts of climate change on secondary activities a literature review气候变化对经济的影响二次活动一个文献综述.pdf
- economic development threats and opportunities经济发展的威胁和机遇.pdf
文档评论（0）