氢氧化钇及氧化钇合成.docVIP

氢氧化钇及氧化钇合成 纺锤形氢氧化钇和氧化钇的微波快速合成、表征及其光学性能研究／黄宜祥等 ·381· 纺锤形氢氧化钇和氧化钇的微波快速合成、表征及其光学性能研究 黄宜祥1，杨德生2，王师金1 (1江西师范大学化学化工学院，南昌330022；2新余四中，新余338000) 摘要 在乙二胺四乙酸二钠(EcrrA)存在的条件下，用微波加热法快速合成了大量纺锤形氢氧化钇。考察了 微波加热时间对合成的影响。结果表明，微波加热15min可制备形状貌均一且结晶良好的纺锤形氢氧化钇，其颗粒 长度为2．5～4．0t嚏ra，宽度为400～900nm。将纺锤形氢氧化钇在500℃煅烧4h后可得纺锤形氧化钇，同时用相似方 法还成功制备出纺锤形Y2Q：Eu3+，对其光学性能进行了研究，发现当激发波长为465nm时，最强发射峰在 613nm。用XRD、SEM对合成的产物进行了表征，并对纺锤形氢氧化钇形成的机理进行了简单探讨。 关键词 氢氧化钇氧化钇微波发光 中图分类号：06ii．62 文献标识码：A Spindle-like Yttrium Hydroxide and Yttrium Oxide：Microwave Synthesis， Characterization and Photoluminescence Properties 一 HUANG Yixian91，YANG Deshen92，WANG Shijinl (1 College of Chemistry and Chemical Engineering，Jiangxi Normal University，Nanchang 330022； 2 Xin Yu No．4 Middle School，Xinyu 338000) Abstract Spindle-like Y(OH)3 is prepared on alarge scale in short time with the assistance of microwave hea- ting in the presence of disodium ethylenediamine tetraacetate(E】DTA)．The effect of microwave heating time on the synthesis is investigated in details．The results showthat uniform andwell crystallized spindle-like Y(OH)3 can be ob— rained in 15rain．The spindle-like products are in a length of 2．5tan to 4．0vxn and awidth ranging from 400rim to 900rim．The spindle-like Y(OH)3 is converted to spindle-like Yz()3 after thermal decomposition at 500C for 4h Spin- die-like Y203：Eu3+powder is also prepared and the photoluminescence(PL)properties are studied．Under the exci— tation of 465nm light，the most intense emission peak locates at 613nm．The products are characterized by X-my dif— fraction(XRD)，scanBjIlg electron micr