Teo的C2模型与其它稠合规则之间关系的研究.pdfVIP

• 184 • 化学通报 2ω年第2 期 h忧p:/I www .hxtb .org Teo 的~模型与其它稠合规则之间关系的研究 企成树 (黑龙江绥化学院化学与制药工寝蕉 属龙江绥化 15拙。 摘 要 提出了一个稠合型簇合物的稠合规则，讨论了磨氏拓扑结构规则和 Min伊稠合规则的推广，扩 2 大了两个稠合规则的应用范围。研究了在稠合型簇食物中 Teo 的 c 模型与 Mingoø 稠合规则、推广的磨氏拓 扑结构规则和本文提出的稠合规则之间的关系。同时，利用提出的稠命现簇合物的稠合规则导出了越级簇合 物 clusters of clusters 中原子和电子之间存在的魔数关系。 2 模型工十丽体庸氏拓扑结构规则 关键诩 稠合型簇合物 Teo 的 C Ming08 稠合规则 Study on the RelatioDS between Teo s ê Model and other Condensation Rul，ω Jin Chengshu (De阳X阳ent of Chemistry and Phsrmacel且tical Engin时，ring ， Suihua University , Suíhua 152创1) Abstrad 币le oondensation rule of condensed transítion metal clusters w倒 set up. 咧te problems a.bout the 萨可pularization of Ti皿晤， sω，pologícal structural rule and Mingo s coooensation rule were discussed in condensed transítion metal clusters and 出e appliωtion range of them wωextended.， 币1e relations between 由e脚 condensation rules wi由 Teo s C: model were also discussed. Meanwhile , the general fonnul嗣 for ma事ic numbers in 脚，m and ele础。n counting of clusters o( clustωsm咆 derived Crom the suggested conden幽.tion rule. 币M 叫剧tion for cal创.ùating the number of valent elcctrons of condensed transition nte时 clus饭:rs is gíven by NVE = 2( 川风+习风 +m 响 0 3po - 3 凡四川…9 凡川、) Where , NVE is the nun也er of valent electrons of clu脚睛， S. is theω咄阳础er of tra汹汹on metal