灰化条件对稻壳灰和稻秆灰理化特性的影响-农业生物技术学报.PDF

第36 卷 第6 期 中 国 电 机 工 程 学 报 Vol.36 No.6 Mar. 20, 2016 2016 年3 月20 日 Proceedings of the CSEE ©2016 Chin.Soc.for Elec.Eng. 1633 DOI ：10.13334/j.0258-8013.pcsee.2016.06.017 文章编号：0258-8013 (2016) 06-1633-10 中图分类号：TK 6 灰化条件对稻壳灰和稻秆灰理化特性的影响 姚锡文，许开立 ( 东北大学资源与土木工程学院，辽宁省 沈阳市 110819) Effect of Ashing Conditions on Physicochemical Properties of Rice Husk Ash Straw Ash YAO Xiwen, XU Kaili (School of Resources Civil Engineering, Northeastern University, Shenyang 110819, Liaoning Province, China) ABSTRACT: The physicochemical characteristics of rice husk 能谱分析等实验方法研究了不同灰化温度(600 和 815 ℃)下 ash (RHA) and rice straw ash (RSA) obtained at different 制得的稻壳灰和稻秆灰的理化特性。通过马弗炉灼烧实验考 ashing temperatures (600 ℃ and 815 ℃) were studied by X-ray 察了灰化温度和灰化时间对稻壳和稻秆灼烧后的灰分量及 fluorescence spectrometry, X-ray diffraction analysis, scanning 其表观形貌的影响，并基于灰成分对2 种生物质灰的结渣特 electronic microscopy and energy spectrum analysis. Muffle 性进行对比分析。结果表明：不同灰化条件对生物质灰的灰 furnace burning experiment was used to study the influence of 分量、灰组成、灰熔点、物相变化和积灰结渣等特性均有较 ashing temperature and ashing time on the ash contents and 大影响；灰分量随着灰化温度和时间的增加而降低，稻壳灼 apparent morphology of rice husk and rice straw. Based on the 烧后的灰分量明显高于稻秆；灰化温度高于600 ℃时，灰样 ash composition results, contrastive analysis on sintering 逐渐出现烧结结构，815 ℃时灰颗粒表面逐熔融，黑色碳颗 characterision of biomass ash was also conducted. The results 粒逐渐暴露而被氧化去除；相同温度下灼烧，2 种灰的颜色 show that different burning conditions have a remarkable effect 均由黑变为灰白，最后呈浅红色；稻秆灰中K 、Na 、Ca 等 on the ash contents, ash composition, ash fusion points, phase 碱金属和Cl 含量明显高于稻壳灰，更易造成设备腐蚀；灰 transformation and slag-bonding. The ash contents decrease 化温度对灰的结渣特性影响较小；600