钯纳米粒子嵌入金属有机框架：合成、结构特征和氢吸附性能.pdfVIP

Published on Web 02/15/2010 Pd Nanoparticles Embedded into a Metal-Organic Framework: Synthesis, Structural Characteristics, and Hydrogen Sorption Properties Claudia Zlotea,† Renato Campesi,† Fermin Cuevas,† Eric Leroy,† Philippe Dibandjo,‡ Christophe Volkringer,§ Thierry Loiseau,§ Ge´rard Fe´rey,§ and Michel Latroche*,† Institut de Chimie et des Materiaux de Paris-Est, CNRS UMR 7182, 2-8, Rue Henri Dunant, 94320 Thiais, France, Institut de Sciences des Mate´riaux de Mulhouse, CNRS, 15, Rue Jean Starcky, 68057 Mulhouse, France, and Institut LaVoisier, UMR CNRS 8180, UniVersite´ de Versailles Saint Quentin, 45, AVenue des Etats-Unis, 78035 Versailles Cedex, France Received October 15, 2009; E-mail: michel.latroche@icmpe.cnrs.fr Abstract: The metal-organic framework MIL-100(Al) has been used as a host to synthesize Pd nanoparticles (around 2.0 nm) embedded within the pores of the MIL, showing one of the highest metal contents (10 wt %) without degradation of the porous host. Textural properties of MIL-100(Al) are strongly modified by Pd insertion, leading to significant changes in gas sorption properties. The loss of excess hydrogen storage at low temperature can be correlated with the decrease of the specific surface area and pore volume after Pd impregnation. At room temperature, the hydrogen uptake in the composite MIL-100(Al)/Pd is almost twice that of the pristine mater