微波炉用铜管防氧化方法的研究.docVIP

微波炉用铜管防氧化方法的研究 摘要氧化变色是纯铜管生产中常见的一种质量缺陷，也是铜管加工厂家普遍遇到的一个质量方面难题。氧化变色是指纯铜管内外表面受外界因素影响, 在生产、运输过程中或生产后放置一段时间, 失去原有的带金属光泽的紫红色而变色或产生黑斑的现象。结合厂家需求，本课题围绕微波炉用纯铜管冷加工后的表面氧化机理、防治措施与方法开展研究，选用清洗剂与防锈剂对铜管进行处理，并对铜管表面通过宏观形貌，扫描电子显微镜(SEM)，X射线光电子衍射分析(XPS)， X射线衍射谱分析(XRD)及能谱等实验手段进行观察与分析，力图提供一套有效延迟纯铜管氧化变色的工艺及后期保存路径，为纯铜管氧化变色的缓解研究提供相应的理论支持。但同时在实验过程中也遇到一些问题因为试样表面的氧化膜非常薄,光检测试样表面的氧化膜是比较困难的,有时检测到的是只有基体铜,比如在做XRD时就是这样。这需要寻求另外的方法来解决。11573 关键词纯铜管氧化变色缓解氧化 毕业设计说明书（论文）中文摘要 TitleThe study of antioxidation methods of copper pipes used for microwave ovens Abstract Oxidation discoloration is a common form of quality defects in the production of copper tubes, and is a quality problem manufacturers have generally encountered .Besides, oxidation discoloration is the phenomenon that the internal and external surfaces of copper subject to external factors placed some time after the production, transportation and loss the original with a metallic cluster purple discoloration or darks pots. In accordance with manufacturerrsquo;s demand, this topic around the microwave surface oxidation mechanism of copper tubes, cold control measures and methodscarry out the research, using the orthogonal experimental design, selection of cleaning agents and rust inhibitors to deal with thepipes. Surface was observed and analyzed through experimental means of macro-morphology, SEM, XPS, XRD and EDS, trying to provide an effective way to delay the tubes oxidation discoloration process and post-save path for the tubes oxidation discoloration mitigation and the corresponding theoretical support. During the experiment, at the same time some problems are encountered because the sample surface oxide film is very thin, and sometimes detected only the matrix copper. This needs to seek another way to solve. 参考文献19 1绪论 1.1课题背景 铜及铜基合金以其优良的电性能和美丽的外观而被广泛应用于导电材料、包装材料、仪器仪表等方面[1]。在铜与其他混合元素中，铜的电位比较低，电位较负的一方在湿度比较大的环境中更容易被氧化而导致变色现象的发生[2]。氧化变色同时也是是微波炉用铜管生产中常见的一种质量缺陷，也是铜管加工厂家普遍遇到的一个质量难题。而氧化变色是指铜管内外表面受外界因素影响,如温度，外界环境湿度及自身铜的纯度[3]。 在生产、运输过程中或生产后放置一