稀土掺杂纳米磁性材料的制备.docVIP

稀土掺杂纳米磁性材料的制备 摘要本采用LCS法掺杂Ce离子制备纳米尖晶石铁氧体，借助X-射线衍射分析（XRD）、红外光谱(FT-IR)和透射电镜电镜（TEM）对产物的晶型结构、粒径以及形貌特征进行表征分析，讨论了掺杂不同含量稀土离子与烧结温度对铁氧体结构和粒径等的影响，在此基础上确定合适的烧结工艺，为今后研究其它稀土元素在铁氧体中的应用和开发奠定了基础。本文首先通过加入两种不同燃料体系进行实验对比后，发现采用碳酰胺燃料作为还原剂时，试样粒径较大，并且由于燃烧温度较高，容易团聚和产生少量氧化铁；采用水溶性肼类燃料作为还原剂时，由于其较大的放气量和络合性能，使得产物粒径较小、晶型较完美、分散性较佳。然后通过研究工艺条件对产品的影响，发现制备目标产物，加入适量助剂后，煅烧温度为800℃时，产品性能最佳。最后以改进后的LCS最佳合成工艺合成出NiFe2-xCexO4关键词尖晶石铁氧体，LCS法，粒径11405 毕业设计说明书（论文）外文摘要 TitleNanometer magnetic materials were prepared by doping with rare-earth Abstract In this work, spinel ferrites were prepared by doping with Ce rare-earth ions using LCS method .The product was characterized by X- ray diffraction analysis ( XRD ), Infrared Spectroscopy ( FT-IR ) and Transmission Electron Microscopy ( TEM ) .The effect of different doped contents and sintering temperatures on the microstructure and grain size of Ni-Fe ferrites were discussed. On this ground, the optimal sintering process has been determined, which has laid the foundation for the application and exploitation of ferrites doped other rare-earth elements. Firstly, the two different fuel systems are improved by adding complex agent and dispersant .The results show that the sample size is large when using urea fuel, and it is easy to agglomerate and produce a small amount of iron oxide because of the high combustion temperature ; instead, the sample size is small ,the products have better dispersivity and the crystal is more perfect when using the water-soluble hydrazine fuel as the reducing agent, which due to its larger discharge capacity and complexation　.Then, the effect of operation conditions were studied and found the optimal properties of preparing each 1g products were as follows: adding complex agent and dispersant ,and the calcination temperature is 800℃. Finally, NiFe2-xCexO4 is prepared by the improved LCS method. 致谢24 参考文献25 1 绪论 1.1 课题背景 纳米技术是本世纪前二十年的主导技术，纳米材料又是纳米技术的核心。磁性材料这个用途十分广泛的功能材料，自20世纪80年代起也随着纳米技术的发展渐渐向新型纳米磁性材料发展起来。纳米科技的发展给传统磁性产业带来了跨越式发展的重大机遇和