牺牲棉纤维模板法制备褶皱状SnO2负极材料及其电-无机材料学报.PDF

第29 卷 第 11 期 无 机 材 料 学 报 Vol. 29 No. 11 2014 年11 月 Journal of Inorganic Materials Nov., 2014 文章编号: 1000-324X(2014)11-1127-06 DOI: 10.15541/ji 牺牲棉纤维模板法制备褶皱状 SnO2 负极材料及其电化学性能 吁 霁, 夏 媛 ( 南昌大学 化学学院, 南昌330031) 摘 要: 以棉纤维作为模板, 制备褶皱层状 SnO 。通过XRD 、SEM、TEM 、CV、恒流充放电、EIS 等测试手段对 2 材料结构、形貌和电化学性能进行了表征。结果表明: 产物具有由粒径 16~21 nm 的SnO2 纳米颗粒构成的褶皱状 形貌。电化学测试表明该材料在电流密度70 mA/g 时循环50 次后放电比容量仍高达614 mAh/g, 甚至在电流密度 为3000 mA/g 时放电比容量仍达到405 mAh/g, 表现出优异的循环性能和倍率性能。 关 键 词: SnO2 ; 棉纤维; 模板法; 褶皱结构; 锂离子电池 中图分类号: TQ174 文献标识码: A Synthesis of Corrugated SnO by Cotton Fibers Template Method and Its 2 Electrochemistry Performance YU Ji, XIA Yuan (Nanchang University, Department of Chemistry, Nanchang 330031, China) Abstract: Corrugated SnO was prepared by an effective template using cotton fibers which were sacrificed during 2 preparation. The as-prepared SnO2 samples were characterized by XRD, SEM, TEM, CV, galvanostatical method and EIS. The results show that the corrugated SnO2 is composed of nanopaticles with size of 16-21 nm. The as-obtained corrugated SnO2 electrodes can deliver a discharge capacity of 614 mAh/g at current density of 70 mA/g after 50 cycles. Even at the current density of 3 A/g the products can still deliver a high reversible discharge capacity of 405 mAh/g. As lithium storage mater