纳米材料的改性.docVIP

学校代码： 11059 学 号：0703021044 合肥学院 Hefei University 毕业论文（设计） BACHELOR DISSERTATION 论文题目： Y23:Eu3+/PMMA纳米复合材料 制备及性能研究 学位类别： 工学学士 学科专业： 化学工程与工艺 作者姓名： 陈 龙 导师姓名： 杨本宏 完成时间： 2011年6月4日 纳米Y2O3:Eu3+/PMMA复合材料制备及性能研究 中文摘要 纳米Y2O3:Eu3+作为一种多功能无机纳米粒子，近年来由于其突出的物理和化学性能以及对紫外线和红外线的强吸收近而受到越来越多的关注。必须选择合适的方法合成Y2O3:Eu3+，用KH-151对其进行表面改性后，将其与甲基丙烯酸甲酯 (MMA) 进行本体聚得到一种新的复材料Y2O3:Eu3+/PMMA。主要研究内容如下： (1) 对Y2O3:Eu3+/高分子复合材料的制备方法及性能进行了综述。 (2) 用水热法制备出纳米Y2O3:Eu3+，用FTIR、XRD、SEM、荧光表征观察纳米颗粒的结构和发光性能。实验结果表明制备的纳米Y2O3:Eu3+基本的符合Y2O3: Eu3+的XRD标准谱图，证明制备的单掺样品无杂相存在，荧光测试显示在613纳米处出峰，这与在紫外灯照射下发射红光相符。 (3) 用KH-151对其进行表面改性， FTIR表征结果表明乙烯基已经嫁接到纳米颗粒上。 (4) 表面改性的Y2O3: Eu3+与甲基丙烯酸甲酯本体共聚，制Y2O3:Eu3+/PMMA复合材料对复合材料进行FTIR、XRD、SEM表征。使用TGA对纳米复合材料的热性能进行分析，利用万能试验机对材料的拉伸强度进行测试。实验结果表明，纳米颗粒已经均匀地分布在复合材料中，热分析和力学测试后表明复合材料的热性能和力学性能优于有机玻璃的性能。 关键词：Y2O3:Eu3+；PMMA；复合材料；本体聚合法；热性能；力学性能 Abstract Nano-Y2O3:Eu3+, as one of the multifunctional inorganic nanoparticles, has drawn increasing attention in recent years due to its prominent physical and chemical properties, such as intensive ultraviolet and infrared absorption. Inorganic composite materials can be both functional and processability of polymer materials, which attracted much attention. Y2O3:Eu3+ was synthesized by hydrothermal process and then modified by KH-151. The modified Y2O3:Eu3+ was blended with MMA and underwent in situ polymerization to prepare a series of new PMMA / Y2O3:Eu3+ bone repair nano-composites. Their structures were characterized using FTIR and XRD, respectively. The thermal properties of m- Y2O3:Eu3+、Y2O3:Eu3+/PMMA nano-composites were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The main research contents are as follows: (1)Y2O3:Eu3+ nano-particles on the preparation method and nano-composites are reviewed. (2)Nano-Y2O3:Eu3+was prepared by hydrothermal method. The nano structure and luminescence properties of as-synthesized Y2O3: Eu3 + were observed by the XRD, SEM, an