准东煤中碱金属的赋存形态及其在热解过程中的-中国电机工程学报.PDF

第 34 卷 增刊 中 国 电 机 工 程 学 报 Vol.34 Supplement Nov.20, 2014 130 2014 年 11 月 20 日 Proceedings of the CSEE ©2014 Chin.Soc.for Elec.Eng. DOI ：10.13334/j.0258-8013.pcsee.2014.S.018 文章编号：0258-8013 (2014) S-0130-06 中图分类号：TK 123 准东煤中碱金属的赋存形态 及其在热解过程中的迁移规律 王智化，李谦，刘敬，黄镇宇，周志军，周俊虎，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) Occurrence of Alkali Metals in Zhundong Coal and Its Migration During Pyrolysis Process WANG Zhihua, LI Qian, LIU Jing, HUANG Zhenyu, ZHOU Zhijun, ZHOU Junhu, CEN Kefa (State Key Laboratory of Clean Energy Utilization (Zhejiang University), Hangzhou 310027, Zhejiang Province, China) ABSTRACT: Method of three-step-extraction was used to 关键词：准东煤；碱金属；赋存；热解；迁移 research the existing form of alkali metals in Zhundong 0 引言 Coal. Coal samples were placed in the tube furnace which was in inert atmosphere to study the migration of alkali metals 准东煤田预测储量 3900 亿 t ，按照 2013 年我 varying with temperature from 400 to 1000 ℃. Finally, the 国37 亿 t 的煤炭产量计算，可够全国使用近百年。 release forms of alkali metals from coal ash 但目前各电厂在燃用准东煤过程中，均出现了严重 during pyrolysis process were simulated by Factsage. The 的炉内结渣、尾部受热面沾污堵塞的问题[1] 。而准 results show that sodium in Zhundong coal exists mainly in the 东煤的问题可能跟煤中高的钠含量有关，因此研究 form of water soluble sodium, while potassium is in the form of organic potassium and insoluble potassium. The content of 准东煤中钠钾碱金属在煤中的赋存形态及其在热 water soluble sodium in Zhundong coal descends obviously in 转化利用过程中的迁移释放规律，对于准东煤的燃 the process of pyrolysis and the release rate is the fastest at the 烧利用意义重大。 temperature between 400 to 800 ℃, While the concentration 对于碱金属在煤中赋存形态的研究，张守玉等 of water soluble potassium is stable. Repla