12 TransitionMetals 1 Penn State University（12 TransitionMetals 1宾夕法尼亚州立大学）.pdfVIP

TransitionTransition MetalsMetals Chapter 22 Transition Metals 1 Transition Metals: Occupy the d-block of periodic table Have d-electrons in valence shell Some characteristics of Transition Metals and their compounds: 1. Exhibit more than one oxidation state 2. They form an extensive series of compounds known as metal  compllexes or coordidinatition compoundds. 3. Transition metals exhibit interesting magnetic properties. 4. Many of their compounds are colored. 55. TransitionTransition metalsmetals playplay importantimportant rolesroles inin biologicalbiological systemssystems andand  modern technology. Transition Metals 2 There are periodic trends in the transition metals, butbut theythey areare oftenoften complexcomplex (product of several factors, some working in opposite directionsdirections – ee.gg. combiningcombining thethe effectseffects ofof increasingincreasing nuclearnuclear chargecharge withwith the presence of nonbonding d electrons) Lanthanide contraction – similarity in size, behavior, ppropperties of 4d and 5d transition elements We won’t worry about details of periodic trends in the transition metals or the exact reasons for them Transition Metals 3 Recall the Electron Configurations of the transition metals. 2 6 UUse ththe periiodidic ttablble tto gett ellecttron confifiguratitions Ar 3s 3p of the First Row Transition metal ATOMS K [Ar]4s1