A Transformation of anatase into rutile DICP(锐钛矿向金红石DICP的转换).pdfVIP

A Transformation of anatase into rutile DICP(锐钛矿向金红石DICP的转换).pdf

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A Transformation of anatase into rutile DICP(锐钛矿向金红石DICP的转换)

Exercise-Course-XRD.doc 1/12 04/06/2012 A - Transformation of anatase into rutile Anatase and rutile are two distinct phases of titanium dioxide TiO . The stable phase is rutile. 2 1. Structural study Anatase: tetragonal system. (see PDF file) 1.1 Determine the Bravais lattice. Determine the number Z of chemical formula per unit cell. 1.2 Determine the position of the most intense diffraction peak for λ (Cu K ). α Rutile: tetragonal system (see PDF file) 1.3 Determine the Bravais lattice. 1.4 Determine the indices and the line parameter of the line defined by the points 1 0 0 and 1 1 2. 1.5 Determine the angle between the lines [1 0 0] and [ 1 1 2]. 1.6 Determine the indices of the plane family containing the lines [1 0 0] and [1 1 2]. 1.7 Determine the Miller indices of the plane containing the points 1 0 0, 1 1 2 and -1 0 0. 2. Experimental study The sample holder is a circular silicon wafer (face 511) with diameter 50 mm. The powder is sieved and homogeneously spread on the wafer on a circular area with diameter 35 mm. The recording parameters are: - Sample holder: Si wafer (face 511), diameter 50 mm - Mass of the sample: 30 mg - Diameter of the sample: 35 mm - recording : 10 to 80 ° 2θ - step : 0.04 ° 2θ - dwell time for one step : 2 s - λ(CuKα1) : 1.5405981 Å - Fixed slit opening 0.6 ° - Sampl

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