A review of the current state of biodiesel （回顾当前状态的生物柴油）.pdfVIP

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A review of the current state of biodiesel （回顾当前状态的生物柴油）.pdf

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A review of the current state of biodiesel （回顾当前状态的生物柴油）

REVIEW A Review of the Current State of Biodiesel Production Using Enzymatic Transesteriﬁcation Lene Fjerbaek, Knud V. Christensen, Birgir Norddahl Institute of Chemical Engineering, Biotechnology and Environmental Technology, ´ University of Southern Denmark, Niels Bohrs Alle 1, DK-5230 Odense M, Denmark; telephone: þ45-6550-7443; fax: þ45-6550-7443; e-mail: lfj@kbm.sdu.dk Received 29 October 2008; accepted 16 December 2008 Published online 8 January 2009 in Wiley InterScience (). DOI 10.1002/bit.22256 triglycerides (TAG) need to be chemically altered to fatty ABSTRACT: Enzymatic biodiesel production has been acid alkyl esters (FAAE) to be useful as biodiesel fuel for investigated intensively, but is presently employed indus- currently used diesel engines (Ma and Hanna, 1999; Meher trially only in a 20,000 tons/year pilot plant in China (Du et al., 2006; Mittelbach et al., 1983; Pryde, 1983; Srivastava et al. [2008] Appl Microbiol Technol 79(3):331–337). This and Prasad, 2000). review presents a critical analysis of the current status of Catalysts investigated for transesteriﬁcation are either research in this area and accentuates the main obstacles to the widespread use of enzymes for commercial biodiesel acids, bases, both liquid and heterogeneous, as well as free or transesteriﬁcation. Improved results for enzymatic catalysis immobilized (imm.) enzymes (Haas et al., 2006; Kaieda are seen with respect to increased yield, reaction time and et al., 1999; Komers et al., 2001; Ma and Hanna, 1999; Meher stability, but the perfor