8-羟基喹啉锗印迹聚合物合成及选择性吸附锗研究-副本.docVIP

8-羟基喹啉锗印迹聚合物合成及选择性吸附锗研究 曹洪杨1,2,3，金明亚1,2，张魁芳1,2，陶进长1,2，朱薇1,2,3，刘志强1,2,3 （1.广东省稀有金属研究所，广州 510651；2.广东省稀土开发及应用重点实验室，广州 510651； 3. 稀有金属分离与综合利用国家重点实验室，广州 510651） 摘要：以8-羟基喹啉和四氯化锗为模板，采用杂化沉淀聚合法制备了8-羟基喹啉锗印迹聚合物微球MIPs微观结构及孔径分布，推测了8-羟基喹啉锗印迹聚合物合成过程对MIPs对锗离子的吸附性能进行了研究。结果表明，MIPs具有大比表面积170.32 m2/g）、微观多孔的纳米微球结构吸附时间延长、溶液中初始锗含量提高，MIPs对锗离子的选择性吸附能力提高，当吸附时间2 h、溶液中初始锗浓度为0.5 mg/m时，MIPs对锗的吸附率达到最大96.84%，MIPs对锗离子具有显著吸附选择特。 关键词：8-羟基喹啉；锗；杂化沉淀聚合；印迹聚合物；吸附 文献标志码：A 文章编号：1007-7545（2017）09-0000-00 Study on Synthesis of 8-Hydroxyquinoline-Germanium Imprinted Polymer and Its Selective Adsorption of Germanium CAO Hong-yang1,2,3, JIN Ming-ya1,2,3, ZHANG Kui-fang1,2,3, TAO Jin-zhang1,2,3, ZHU Wei1,2,3, LIU Zhi-qiang1,2,3 (1.Guangdong Research Institute of Rare Metals, Guangzhou 510651,China； 2. Guangdong Province Key Laboratory of Rare Earth Development and Application, Guangzhou 510651, China 3.State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510651,China) Abstract：Microspheric 8-hydroxyquinoline-germanium ion imprinted polymer MIPs) was prepared by hybrid precipitation polymerization method with 8-hydroxyquinoline and germanium tetrachloride as template. Microstructure and pore size distribution of MIPs were characterized. Synthesis process of imprinted polymer was speculated. Adsorption performance of MIPs was analyzed. The results show that MIPs has large specific surface area (170.32 m2/g), and micro porous nanometer microspheres structure. Selective adsorption ability of MIPs for germanium ion is improved with increase of adsorption time and initial germanium content in solution. Adsorption rate of germanium with MIPs is 96.84% under the conditions of adsorption time of 2 h and initial concentration of germanium of 0.5 mg/mL. MIPs has remarkable selective adsorption ability for germanium ion. Key words：8-hydroxyquinoline; germanium; hybrid precipitation polymerization; imprinted polymer; adsorption 锗广泛应用于电子工业半导体器件等高新技术领域[1]，锗的提取分离主要采用高温挥发、湿法浸出、蒸馏提取、液液萃取、离子交换等