硅铬合金（Chromium silicon alloy）.doc

硅铬合金（Chromium silicon alloy） EDTA titrimetric method for the determination of aluminium content 1 range This standard specifies the method, content, reagent, material, instrument and equipment, analysis procedure and calculation result of EDTA titrimetric method for the determination of aluminium content. This standard applies to the determination of aluminium content in silicon chromium alloy, measuring range (quality fraction): 0.30%--2.50%. 2 method summary The sample with nitric acid and hydrofluoric acid dissolution, the four generation of silicon silicon fluoride, perchloric acid smoking is exhausted, solution with ammonia separation to remove iron chromium, sodium hydroxide, and then adding an excess of EDTA, on the condition of PH5-6, with PAN as the indicator for titration of copper sulfate standard solution over the amount of EDTA, adding fluoride take sodium aluminum, EDTA and copper sulfate standard solution titration released, according to second times the amount of consumption of copper sulfate, calculate the mass fraction of aluminum. 3 reagent 3.1 ammonium nitrate (solid) 3.2 boric acid (solid) 3.3 nitrate (1.42g/mL) 3.4 hydrofluoric acid (1.15g/mL) 3.5 perchloric acid (1.67g/mL) 3.6 ammonia (0.90g/mL) 3.7 hydrochloric acid solution (1+1) 3.8 sodium hydroxide solution (250g/L) stored in a plastic bottle 3.9 sodium fluoride solution (50g/L) stored in plastic bottles. 3.10 buffer solution: weigh 200g ammonium acetate in 300mL beaker, add 10mL acetic acid (1.05g/mL), dissolved, dilute with water to 1000mL and mix. 3.11 ammonium nitrate lotion (10g/L) 3.12 phenolphthalein (2g/L) with ethanol solution (3+2) preparation. 3.13 PAN indicator (1g/L): ethanol preparation. 3.14 EDTA standard solution (0.01mol/L) 3.15 standard solution of copper sulphate (0.01mol/L) 4 sample Q/SJFC.J08-011.4-2008 The specimen shall pass through the 0.125mm screen. 5 analysis steps 5.1 sample quantity Weigh 0.25g sample, accurate to 0.0001g. 5.2 blank test Along with the sample b