红外光谱的分析（Analysis of infrared spectrum）.docVIP

红外光谱的分析（Analysis of infrared spectrum） [experience] how to analyze the infrared spectrum of the hand already obtained According to the following steps: AP AP (1) based on the spectra of carbon compounds launch frame type: according to the formula calculating formula of saturation: The brand of the brand is not saturation (T-O) = F+1+ /2: The brand of the brand: F valence atomic number 4 valence (C atoms), AP: T valence atomic number 3 valence (N atoms), AP O: the number of atoms of 1 valence valence (H atoms), The brand of the brand such as: such as benzene: C6H6, unsaturation = 6+1+ (0-6) /2 = 4, 3 double bonds with a ring, just as 4 degree of unsaturation; The brand of the brand (2) analysis of 3300~2800 cm-1 region C-H stretching vibration absorption; with a cut-off of 3000 cm-1 higher than 3000 cm-1 for unsaturated carbon C-H stretching vibration absorption, has the potential to alkene, alkyne, aromatic compounds, and is generally less than 3000 cm-1 saturated C-H stretching vibration absorption; The brand of the brand (3) in slightly higher than the 3000 cm-1 absorption, should be in the 2250~1450 cm-1 frequency region analysis of unsaturated carbon carbon bond stretching vibration absorption peaks, which: The brand of the brand by 2200~2100 cm-1 The brand was 1680~1640 cm-1 The brand of aromatic ring cm-1 1600158015001450 If the brand of the brand has been identified as alkenyl or aromatic compounds should be further analysis of fingerprint region. 1000~650 cm-1 frequency region, to determine the number and position of the substituents (CIS, ortho, meta and para); The brand of the brand (4) carbon skeleton type is determined, according to other functional groups, such as C=O, O-H, C-N and other functional groups to determine the characteristic absorption of compounds; The brand of the brand (5) analysis should pay attention to the description of each functional group of correlation peaks linked to accurately determine the existence of functional groups, such a