萃取催化动力学分析法测定痕量钯（Determination of Trace Palladium by Extraction Catalytic Kinetic Analysis）.doc

萃取催化动力学分析法测定痕量钯（Determination of Trace Palladium by Extraction Catalytic Kinetic Analysis） 1994 analysis laboratory, volume third, thirteenth Determination of trace amounts by Extraction Catalytic Kinetic Analysis A (Department of chemistry, Huaibei Coal Industry Teachers College, Huaibei 235000) This paper studies in P H 3 . 0 buffer solution was used to catalyze dissolved oxygen and oxygen in aqueous solution using phenanthrene and phenanthrene Rowling activation Pd (I) A method for the kinetic analysis of the extraction of trace yellow sulfur (two) was established . Sensitivity of method For 3.3 X I. A g / m L, linear range of 7.5 X, 1 0-, 4 . O X 10- g / m L. Used in the determination of a catalyst Got a satisfactory result. Keywords Si; two benzene sulfur Leather Knee; catalytic kinetic analysis Because of the high sensitivity, simple equipment and simple operation, the kinetic analysis method is simple Rather, people pay more attention to it. Determination of trace amounts by kinetic analysis Not much, [lj . Most of them are catalyzed by Pd (L) and hypophosphite is reduced to inorganic Reagent and organic reagent system. In this paper, Rowling n (P, h, e) is used to activate P D (L) catalyzes the oxidation of two phenyl sulfur glands (H, Z, D, z) in water by dissolved oxygen The reaction is indicated by extraction equilibrium, and the reaction time and H ZD Z in aqueous phase are controlled The concentration, which makes it a pseudo first order reaction, was established by conditional test Kinetic method for the determination of trace amounts by extractive catalysis. Reaction machine A preliminary discussion has been carried out . A catalyst used in an active carbon as a carrier The result is satisfactory. 1 instruments and reagents D MS Type 200 ultraviolet visible spectrophotometer; type 721 spectral light H S I 2 type acidity meter. Pd (n) standard solution: 1 mix g / m L . Take the spectrum pure 1. 00 G, add concentrated nitric acid heating, dissolve, and