少量铟对铅合金在硫酸溶液中阳极行为的影响.PDF

少量铟对铅合金在硫酸溶液中阳极行为的影响 1 2 何启贤 袁学韬 （1.广西现代职业技术学院，河池 547000 ； 2.北京有色金属研究总院，北京 100088） 摘要：采用动电位法研究纯Pb 与 Pb-0.6%In 合金阳极在 4M H SO 溶液中的阳极 2 4 极化行为；用 X 射线衍射（XRD ）、能谱分析（EDS ）和扫描电子显微镜（SEM）分析 了阳极极化过程中铅及铅铟合金表面的腐蚀层成分和微观组织结构。结果表明：纯Pb 及 Pb-0.6%In 合金电极的阳极行为都存在活化/钝化过渡区，铟的掺入有利于 Pb(II) 向 Pb(IV) 的转化，降低腐蚀产物层中 PbSO4 和 PbO 的含量，并有利于铅电极表面形成高 电化学活性的腐蚀层。因此向铅中添加铟有利于改善铅酸电池的充放电过程。 关键词：铅铟合金，阳极极化，阳极电位，腐蚀层 EffectsofMinor InontheAnodicBehaviorofthe Lead Alloy in the H SO 2 4 Solution HEQi-xian1 YUANXue-Tao2 (1. Guangxi Modem Polytechnic College,Hechi 547000,China; 2. General Research Institute for Nonferrous Metals, Beijing 100088, China) Abstract: The influence of indium on the anodic behaviour of Pb-In alloys in 4 M H SO 2 4 solution is investigated by potentiodynamic techniques. The composition and microstructure of the corrosion layer on Pb-0.6%Inalloys are characterized by X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy analysis (EDS) and scanning electron microscopy (SEM). The potentiodynamic curves show that the anodic behavior of both electrodes exhibits active/passive transition. This study exhibits that indium catalyses the oxidation of Pb (II) to Pb (IV) ，decreases the formation of both PbSO4 and PbO on the surface, and facilitatesthe formation of a more highly electrochemical activity corrosion layer on lead. Therefore, recharge of the battery will be improved due to indium addition to Pb. Key