二氧化碳在水中的溶解度.doc

Aqueous Solubility of CO2 at 101.3 kPa (1 atm) partial pressure[7] Temperature ?DissolvedCO2 volumeper volume H2O grams CO2 per100 ml H2O 0 °C 1.713 0.3346 1 °C 1.646 0.3213 2 °C 1.527 0.3091 3 °C 1.527 0.2978 4 °C 1.473 0.2871 5 °C 1.424 0.2774 6 °C 1.377 0.2681 7 °C 1.331 0.2589 8 °C 1.282 0.2492 9 °C 1.237 0.2403 10 °C 1.194 0.2318 11 °C 1.154 0.2239 12 °C 1.117 0.2165 13 °C 1.083 0.2098 14 °C 1.050 0.2032 15 °C 1.019 0.1970 16 °C 0.985 0.1903 17 °C 0.956 0.1845 ? ? Temperature ?DissolvedCO2 volumeper volume H2O grams CO2 per100 ml H2O 18 °C 0.928 0.1789 19 °C 0.902 0.1737 20 °C 0.878 0.1688 21 °C 0.854 0.1640 22 °C 0.829 0.1590 23 °C 0.804 0.1540 24 °C 0.781 0.1493 25 °C 0.759 0.1449 26 °C 0.738 0.1406 27 °C 0.718 0.1366 28 °C 0.699 0.1327 29 °C 0.682 0.1292 30 °C 0.655 0.1257 35 °C 0.592 0.1105 40 °C 0.530 0.0973 45 °C 0.479 0.0860 50 °C 0.436 0.0761 60 °C 0.359 0.0576 Vapor pressure of solid and liquid P in mm Hg 1 10 40 100 400 760 1520 3800 7600 15200 30400 45600 P in atm (2sf, derived from mm Hg) 0.0013 0.013 0.053 0.13 0.53 1.0 2.0 5.0 10 20 40 60 P in kPa (derived from mm Hg / atm) 0.13 1.3 5.3 13 53 101.325 202.65 506.625 1013.25 2026.5 4053 6079.5 T in °C –134.3(s) –119.5(s) –108.6(s) –100.2(s) –85.7(s) –78.2(s) –69.1(s) –56.7 –39.5 –18.9 5.9 22.4 Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. Annotation (s) indicates equilibrium temperature of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid. For kPa values, where datum is whole numbers of atmospheres exact kPa values are given, elsewhere 2 significant figures derived from mm Hg data. log of Carbon Dioxide vapor pressure. Uses formula: obtained from CHERIC[3]  [edit] Phase diagram [edit] Liquid/vapor equilibrium thermodynamic data The table below gives thermodynamic data of liquid CO2 in equilibrium with its vapor at various temperatures. Heat content data, heat of vaporization, and entropy values are relative to the liquid state at 0°