az31b镁合金表面改性微弧氧化膜的结构及耐蚀性能 structure and corrosion resistance of modified micro-arc oxidation coating on az31b magnesium alloy.pdfVIP

Trans. Nonferrous Met. Soc. China 26(2016) 814−821 Structure and corrosion resistance of modified micro-arc oxidation coating on AZ31B magnesium alloy Xue-jun CUI1,2, Rui-song YANG1,2, Chun-hai LIU1,2, Zu-xiao YU1,2, Xiu-zhou LIN1,2 1. College of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong 643000, China; 2. Materials Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China; Received 23 April 2015; accepted 16 July 2015 Abstract: A hydrophobic surface was fabricated on a micro-arc oxidation (MAO) treated AZ31 Mg alloys via surface modification with myristic acid. The effects of modification time on the wettability of the coatings were investigated using the contact angle measuring device. The surface morphologies and structure of the coatings were evaluated using SEM, XRD and FT-IR. The corrosion resistance was investigated by potentiodynamic polarization curves and long-term immersion test. The results showed that the water contact angle (CA) increases gradually with modification time from 0 to 5 h, the highest CA reaches 138° after being modified for 5 h, and the number and size of the micro pores are decreased. The modification method hardly alters crystalline structure of the MAO coating, but improves the corrosion resistance based on the much positive potential and low current density. Moreover, the corrosion resistance and hydrophobicity can be enhanced with increasing the alkyl chain. The