甲烷在活性炭上吸附平衡模型的研究-燃料化学学报.pdfVIP

第41卷 第3期 燃摇 料摇 化摇 学摇 学摇 报 Vol.41No.3 2013年3月 Journal of Fuel Chemistry and Technology Mar. 2013 文章编号:0253鄄2409(2013)03鄄0380鄄05 甲烷在活性炭上吸附平衡模型的研究 高摇 帅,郑青榕 (集美大学 轮机工程学院,福建省船舶与海洋工程重点实验室,福建 厦门摇 361021) 摘摇 要:比较吸附模型分析甲烷在活性炭上吸附平衡的适用性,为吸附式天然气(ANG)的工程应用提供准确的预测模型。 基于在温度268.15~338.15K、压力0 ~12.5 MPa测试的甲烷在Ajax 活性炭上的吸附平衡数据,选择Langmuir、Langmuir鄄 Freundlich和Toth方程,应用非线性回归拟合方程参数后,确定绝对吸附量和甲烷吸附相态,并比较方程在不同压力区域内的 预测精度。 结果表明,甲烷吸附相密度随平衡温度和压力变化;由绝对吸附量确定的甲烷在Ajax活性炭上的平均等量吸附热 为15.72kJ/ mol,小于由过剩吸附量的标绘结果;Langmuir、Langmuir鄄Freundlich和Toth方程预测结果在0~0.025MPa的累积 相对误差为6.4498%、7.9184%和0.9100%,在1~10MPa为0.4911%、0.1613%和0.3694%。 Toth方程在整个压力范围 内的预测结果最为准确,但Langmuir鄄Freundlich方程在较高压力区域内具有较高的预测精度。 关键词:吸附平衡;甲烷;活性炭;模型 中图分类号:TQ028摇 摇 文献标识码:A Comparisons of adsorption models for methane adsorption equilibrium on activated carbon GAO Shuai,ZHENG Qing鄄rong (ProvincialKey Laboratory of NavalArchitecture Ocean Engineering,Institute of MarineEngineering, Jimei University,Xiamen摇 361021,China) Abstract:Comparisons ofaccuraciesofadsorptionmodelsinpredictingadsorption data of supercriticalmethane on activatedcarbonwerecarriedoutforpracticalapplication ofadsorption ofnaturalgas (ANG). Ajaxactivated carbon was selected as an adsorbent,six isotherms of excess adsorption amount of methane were measured at temperature from268.15 K to 338.15 K and pressure up to 12.5 MPa. Parameters of Langmuir,Langmuir鄄 Freundlich and Toth equationswere firstly setby the linear fit ofadsorption data,absoluteamountsand densities of the adsorbed phase of supercritical methane were then determined by the modified models. Isosteric heats of methane adsorption on Ajax activated carbon were determine