改质聚苯胺对电致色变之影响-国立高雄应用科技大学化学工程与材料.docVIP

中文摘要 本研究在苯胺單體與1 M硫酸水溶液莫耳比1：2製備過程中以界面活性劑(Brij56)進行不同比例之摻雜，經電化學聚合成為高分子膜層；由於摻雜界面活性劑與否以及摻雜不同程度之量，將導致膜層表面型態與內部結構的改變，因此，本研究藉由實驗定量出苯胺單體與界面活性劑重量比為100：2(即2 %界面活性劑) 為最適摻雜量。 當苯胺沈積於ITO玻璃上電聚合形成薄膜後，以三極式電化學分析裝置進行循環伏安測試，觀察其致色/褪色情形與循環壽命，而在測試致色/褪色的過程中以紫外線-可見光(UV-VIS，波長範圍300 mm~800 nm)量測薄膜穿透度之變化，另外，以掃描式電子顯微鏡(SEM)觀察摻雜界面活性劑與否，薄膜表面型態之差異性，進而找出最佳電沈積聚苯胺的操作條件，以製備最佳致色與褪色之光學效應的薄膜並作如下三個不同方向之探討： 1、維持原有的藥品製備與相同界面活性劑摻雜量，在不同溫度50 0C，30 0C，room temperature，10 0C，0 0C，進行電化學沈積，結果顯示低溫(10 0C，0 0C)沉積膜之平整性優於常溫或更高溫。 2、維持原本苯胺單體與酸之比例，並以相同界面活性劑摻雜量，更換不同種類酸(1 M HNO3、2 M HCl與1 M H2SO4)進行製備沈積，結果顯示1 M H2SO4製備沈積膜有較佳可逆性。 3、維持原本苯胺單體及相同界面活性劑摻雜量，改變酸濃度，1 M H2SO4 ，2 M H2SO4，3 M H2SO4，4 M H2SO4，製備沈積液，進行電化學沈積，由實驗得知較高濃度酸有較高膜厚及膜層平整性。 整體而言，以1 M H2SO4製備沈積液並摻雜界面活性劑，除改造了聚苯胺膜層之表面型態而提升了電化學特性與光學特性外，更顯現有較佳的循環壽命。 英文摘要 To proceed adding with different amount of surfactant(Brij56) in the aniline monomer/H2SO4 solution, by electrochemical polymerization to synthesis polymer film in this study. Due to the amount of surfactant in acidic solution, it was found that the morphology and structure of PANI film is quite different, the optimal amount of surfactant is 2 wt %. All electrochemical studies were performed with a three-electrode system. The PANI film were deposited on the ITO glass by electrodeposition in the acid solution . we adopt cyclic voltammetry method to test the colouring and bleaching transition and cycle life of PANI film. The UV-vis spectroscopy (region from 300 nm to 800 nm) was carried out on the process of colouring and bleaching; the morphology of PANI film was observed by SEM, it was found that the difference of morphology between adding and without adding surfactant, it was also the key to find out the optimal conditions for the preparation of PANI film. In order to obtain a better colouring and bleaching film on the optical property, and an optimal route for electron transition on the PANI film by passing current. This work has been focused on the effect of the surfactant added in the acidic solution. There are thre