醋酸乙烯聚合反应系统热失控与安全泄放.pdfVIP

30 5 高 校 化 学 工 程 学 报 No.5 Vol.30 2016 10 Journal of Chemical Engineering of Chinese Universities Oct. 2016 1003-9015(2016)05-1119-08  姜 杰, 张 晨, 柴晓伟, 石 宁, 曹永友 ( 中国石油化工股份有限公司青岛安全工程研究院, 化学品安全控制国家重点实验室, 山东 青岛 266071) VSP2 TMRad 65 Leung Kc Kd X937 TQ342 A DOI 10.3969/j.issn.1003-9015.2016.05.019 Thermal Runaway and Safety Relief of Vinyl Acetate Polymerization Reactors JIANG Jie, ZHANG Chen, CHAI Xiao-wei, SHI Ning, CAO Yong-you (State Key Laboratory of Chemicals Safety and Control, Qingdao Safety Engineering Institute, China Petroleum Chemical Corporation, Qingdao 266071, China) Abstract: Thermal runaway may happen in vinyl acetate polymerization reactors under conditions of excessive initiator and cooling failure, which leads to violent polymerization. Experiments were designed to study thermal runaway and safety relief in typical hazardous scenarios using a bench-scale adiabatic calorimeter VSP2. The results show that excessive initiator is determined as the main factor when comparing peak temperature rising rate, peak pressure rising rate and TMRad under process temperatures. The polymerization reactor is classified as a mild steam system with closed pressure curves. Safe relief rate, flow capacity and the minimum vent area are calculated based on the Leung’s method and ERM model. The calculation results are corrected by correction factor Kc and flow coefficient Kd following real process conditions and the safety vent area is acquired. Key words: vinyl acetate; polymerization; thermal runaway; safety relief 1