磺胺嘧啶在玉米驯化根际土壤中降解规律研究.docVIP

磺胺嘧啶(在玉米驯化根际土壤中降解规律研究 金彩霞，朱雯斐，河南师范大学化学与环境科学学院, 河南省环境污染控制重点实验室，黄淮水环境与污染防治省部共建教育部重点实验室, 河南 新乡453007 关键词 磺胺嘧啶；根际土壤；驯化；降解 Biodegradation regularity of sulfadiazine in acclimated corn rhizospheric soil JIN Caixia , ZHU Wenfei, GUO Hua Key Laboratory for Yellow River and Huaihe River Water Environmental and Pollution Control, Minisitry of Education, Henan Key Laboratory of Environmental Pollution Control, School of Chemistry and Environmental Sciences, Henan Nomal University, Xinxiang Henan 453007 Abstract The degradation of sulfadiazine in different soils, including acclimated and/or original corn soil, rhizospheric and/or non-rhizospheric soil, was investigated by determining its residual concentration with HPLC. The results show that the degradation dynamics of sulfadiazine in soil fitted to the first order reaction kinetics, the degradation rate constant was about 0.043~0.015d-1and the half life was about 16.8~46.5d. The low concentration of sulfadiazine was benefit for its degradation, the degradation rate constant of sulfadiazine increased with its concentration reducing. The difference of degradation rate constant between the rhizospheric and non-rhizospheric soil was significant at the 0.05 probability level. The soil, which had been planted corn previously, promoted the degradation of sulfadiazine significantly. Furthermore, the biodegradability of microbe was enhanced by domestication. On the 20th day, the removal rate of sulfadiazine in the domesticated soil was higher 10 to 23 percent than that without domestication. The result above provides a theoretical feasibility for accelerating the degradation of the sulfonamide in plant acclimated rhizospheric soil. Key words Sulfadiazine Rhizospheric soils acclimation degradation 1 引言50％～90％随粪肥进入到环境中兽药在土壤环境中的降解，自然条件下包括土壤微生物降解、化学降解与光降解三部分，兽药在土壤中发生降解的主要过程有氧化作用、还原作用、水解作用与链接作用等，土壤中兽药降解通常是两个或多个作用的组合。对兽药起降解作用微生物主要有细菌、真菌、藻类、放线菌等[]。目前人们对农药杀虫剂在土壤中的微生物降解特性进行了相关研究，研究表明，对于农药杀虫剂，其在未灭菌的土壤样品中的降解较灭菌的样品中的降解快[2-3]。且种植作物土壤中的有机污染物消