实验七十三__凝固点降低法测定摩尔质量（The freezing point of experiment seventy-three __ reduction method for the determination of molar mass）.docVIP

实验七十三__凝固点降低法测定摩尔质量（The freezing point of experiment seventy-three __ reduction method for the determination of molar mass） Experiment seventy-three determination of molar mass by freezing point reduction method First, preview questions 1. What are the properties of dilute solutions in numbers? What are the properties of dilute solutions and what are the factors involved? A non-volatile solute dissolved in a solvent, the dilute solution drop, vapor pressure, boiling, freezing point osmotic pressure and solute equivalent only on the number of molecules and has nothing to do with the solute species, these four kinds of property are called colligative properties of dilute solution. 2. What are the factors that should be taken into account when determining the molar mass by freezing point reduction? Answer: first of all, the solute can be dissolved very well, when the solute in the solution of dissociation, association, solvation, or formation of complexes, etc., does not apply, generally applicable only to strong electrolyte dilute solution. Secondly, the freezing point should not be too high or too low, should be easy to reach at room temperature. 3, in order to improve the accuracy of the experiment, can we increase the concentration of the solution to increase the T value? Why? Answer, no.. The concentration is too large, will make the solution too quickly coagulation, the concentration is too small, will make the freezing point of the solution is not obvious, the measurement error will increase. 4 、 why should we use air jacket in the experiment? Too cold too much impact on the results? How to control the supercooling degree? Answer, prevent the temperature drop too fast, make the crystallization process easy to observe. Too cold too much affect the accuracy, the error caused by. Add seed or control mixing speed. 5. In the experiment, when naphthalene was added, the naphthalene was accidentally adhered to the tube wall. Whats the effect on the experimental results?