有机物在超临界二氧化碳中的无限稀释扩散系数的测定-大学化学.PDFVIP

大学化学(Daxue Huaxue) January Univ. Chem. 2016, 31 (1), 41–47 41 • 化学实验• doi: 10.3866/pku.DXH 有机物在超临界二氧化碳中的无限稀释扩散系数的测定 陈小娟 钟海敏 余小岚 赖舒慧 陈六平* ( 中山大学化学与化学工程学院，广州 510275) 摘要：利用经改造的超临界流体色谱仪测定不同温度和压力下苯、丙酮在超临界二氧化碳中的无限稀 释扩散系数，开发出一个针对本科高年级学生的开放性实验，旨在加深学生对超临界流体及其性质的 理解。在熟悉超临界流体色谱仪的工作原理、结构及其应用并掌握其操作方法的基础上，拓展学生视 野和思维的深度及广度，提升学生的实验操作技能，培养高素质化学人才。 关键词：超临界流体；二氧化碳；扩散系数；Taylor分散法 中图分类号：O6-339；G64 Measurement of Infinite Dilution Diffusion Coefficients of Organics in Supercritical Carbon Dioxide CHEN Xiao-Juan ZHONG Hai-Min YU Xiao-Lan LAI Shu-Hui CHEN Liu-Ping* (School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China) Abstract: Making use of the modified supercritical fluid chromatograph, we measured the infinite dilution diffusion coefficients of benzene and acetone in supercritical carbon dioxide under different temperatures and pressures, and further develop an opening experiment in order to reinforce students understanding of the supercritical fluid and properties. The depth and breadth of students perspective will be developed. Their experimental skills will be enhanced on the basis of learning operational principle, instrumental structure, application and manipulating method of supercritical liquid chromatograph, which is beneficial to cultivate the high quality chemistry talent. Key Words: Supercritical liquid; Carbon dioxide; Diffusion coefficient; Taylor dispersion method 1 实验背景 1.1 超临界流体及超临界流体色谱概述 当流体的温度和压力分别在其临界温度(T )和临界压力(p )之上时，体系性质均一、处于超