KOH亚熔盐中钒渣的溶出行为 刘挥彬.pdfVIP

23 4 2013 4 Vol.23 No.4 The Chinese Journal of Nonferrous Metals Apr. 2013 1004-0609(2013)04-1129-11 KOH 1, 2, 3 1 1, 2 1 1 1 (1. 100190 2. 100049 3. 100038) KOH 180 4:1KOH 75%700 r/min 300 min1 L/min 95%90% KOH 40.54 50.27 kJ/mol TF 111.3 A Dissolution behavior of vanadium slag in KOH sub-molten salt 1, 2, 3 1 1, 2 1 1 1 LIU Hui-bin , DU Hao , LIU Biao , WANG Shao-na , ZHENG Shi-li , ZHANG Yi (1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China; 3. China Enfi Engineering Corporation, Beijing 100038, China) Abstract The dissolution behavior of vanadium slag was studied by decomposing the slag in KOH sub-molten salt. The effects of reaction temperature, KOH-to-ore mass ratio, particle size and gas flow were examined for obtaining the optimum process parameters. And the dissolution process mechanism was also investigated. The results show that reaction temperature is the most significant factor on vanadium and chromium extraction efficiency. Under the conditions of temperature of 180 , initial KOH-to-ore mass ratio of 4:1, KOH solution content of 75% (mass fraction), stirring speed of 700 r/min, a