锌冶炼重金属物质流向及烟气净化效果研究flowand-化工学报.pdfVIP

锌冶炼重金属物质流向及烟气净化效果研究 1 王学谦, 马懿星, 施勇, 王平, 兰易, 郭晓龙, 王郎郎, 宁平 (昆明理工大学环境科学与工程学院，云南，昆明，650500) 摘要：锌矿焙烧和烟气净化中重金属的物质流向及治理的研究和评价，是冶炼烟气重金属污染控制的重要 基础数据和依据。通过 XRF 、ICP-OES、ICP-MS、双光数显测汞仪检测分析锌矿焙烧物料及烟气中的重金 属含量。结果表明锌精矿焙烧后，58% 以上的Pb 、75% 以上的Cd 随焙砂、收尘进入固态物中，50% 以上的 As 、100%的Hg 进入烟气。烟气经过酸洗和电除雾后，Pb 、Hg 、Cd、As 的去除率分别78.6%、35%、90.9% 和 83.2%，波立登除汞塔深度脱Hg 后，Hg 的去除率达到90.1% 。根据重金属的物质流向和净化效果特征 得出，对于冶炼烟气中 Pb 、Cd 等重金属的去除需要加强除尘，波立登脱汞技术对 Hg 的去除效率高，但要 达标排放还需要技术改进。 关键词: 锌冶炼; 重金属; 物质流; 污染控制 中图分类号：X758 文献标志码：A 文章编号： Flow and purification effect of heavy metal-containing materials in zinc ore smelting process (Faculty of Environmental Science Engineering, Kunming University of Science Technology, Kunming, 650500, Yunnan, China) Abstract: Investigation and evaluation for flow and purification effect of heavy metal-containing materials in zinc smelting processes are important and can provide important basic data for controlling heavy metals in the metallurgical off-gas. Heavy metals involved in the materials of zinc ore smelting and metallurgical off-gas were analyzed by XRF, ICP-OES, ICP-MS and double light display mercury analyzer. The results show that after zinc fine ore roasting, 58% Pb and 75% Cd enter into solid materials of zine calcine and dust, 52% As and about 100% Hg flow into metallurgical off-gas. After acid washing and electrostatic demisting, the removal of Pb, Hg, Cd and As are 78.6%, 35%, 90.9% and 83.2% respectively. After deep removal of mercury by Boliden-Norzink technology, the Hg removal is 90.1%. Based on the characteristics mentioned above for heavy metals flow and purification effect, it should be considered that dust removal process must be enhanced to remove effectiv