石墨烯的制备、能化及在化学中的应用.PDFVIP

物理化学学报(Wuli Huaxue Xuebao) August A cta Phys. Chim. Sin., 2010, 26(8) ：2073-2086 2073 [Review] 石墨烯的制备、功能化及在化学中的应用 耀娟 金 娟 张 卉 吴 萍 蔡称心* (南京师范大学化学与环境科学学院, 江苏省生物功能材料重点实验室, 电化学实验室, 南京 210097) 摘要： 石墨烯是最近发现的一种具有二维平面结构的碳纳米材料, 它的特殊单原子层结构使其具有许多独特 的物理化学性质. 有关石墨烯的基础和应用研究已成为当前的前沿和热点课题之一. 本文仅就目前石墨烯的制 备方法、功能化方法以及在化学 域中的应用作一综述, 重点阐述石墨烯应用于化学修饰电极、化学电源、催化 剂和药物载体以及气体传感器等方面的研究进展, 并对石墨烯在相关领域的应用前景作了展望. 关键词： 石墨烯; 碳材料; 石墨烯氧化物; 石墨烯功能化; 石墨烯应用 中图分类号： O646 Graphene: Synthesis, Functionalization and Applications in Chemistry HU Yao Juan JIN Juan ZHANG Hui WU Ping CAI Chen Xin* (Laboratory of Electrochemistry, Jiangsu Key Laboratory of Biof unctional Materials, College of Chemistry and Environmental Science, Nanj ing Normal University, Nanj ing 210097, P. R. China) Abstract ： Graphene, a recently discovered carbon nanomaterial with carbon atoms tightly packed into a two dimensional honeycomb lattice, possesses many novel and unique physical and chemical properties because of its unusual monolayer atomic structure. Graphene has received a great deal of attention in fundamental and applied research. This review presents the current status of graphene synthesis, functionalization, and applications in chemistry. Specifically, the use of graphene for the fabrication of chemically modified electrodes, the preparation of chemical power sources, catalyst and medicinal matrices, and in gas sensors are summarized. Finally, further applications based on graphene are briefly introduced. Key Wo