苯硫酚盐基溶液的可充镁电池电解液-IngentaConnect.PDF

See discussions, stats, and author profiles for this publication at: /publication/263750595 Benzenethiolate-Based Solutions for Rechargeable Magnesium Battery Electrolytes Article in CT PHYSICO-CHIMIC SINIC · February 2014 DOI: 10.3866/PKU.WHXB201312201 CIT TIONS RE DS 2 43 5 authors, including: Jun Yang Shanghai Jiao Tong University 150 PUBLIC TIONS 6,685 CIT TIONS SEE PROFILE Some of the authors of this publication are also working on these related projects: binder View project PEMFC C T LYSTS ND DEVIECES View project ll content following this page was uploaded by Jun Yang on 05 December 2014. The user has requested enhancement of the downloaded file. 物理化学学报(Wuli Huaxue Xuebao) February Acta Phys. -Chim. Sin. 2014, 30 (2), 311-317 311 [Article] doi: 10.3866/PKU.WHXB201312201 苯硫酚盐基溶液的可充镁电池电解液 卞沛文 努丽燕娜* 再娜甫古丽 杨 军 王久林 (上海交通大学化学化工学院, 上海200240) 摘要: 将4- 甲基苯硫酚、4-异丙基苯硫酚和4- 甲氧基苯硫酚(RSH)分别与格氏试剂C H MgCl/THF(四氢呋喃) 2 5 反应制得的苯硫酚氯化镁(RSMgCl) (分别标记为MBMC、IPBMC 和MOBMC)/THF 和进一步与Lewis 酸AlCl3 反应制得的(RSMgCl) -AlCl /THF (n=1, 1.5, 2)苯硫酚盐基溶液用作可充镁电池电解液, 采用循环伏安和恒电 n 3 流充放电测试研究了电解液的镁沉积-溶出性能和氧化分解电位. 结果表明, 苯硫酚上的基团种类和RSMgCl 与AlCl 的比例对其电化学性能有影响. 其中, 0.5 mol ∙L-1 (IPBMC) -AlCl /