铋钼混合矿低温熔炼新工艺研究-有色金属科学与工程.DOCVIP

铋钼混合矿低温熔炼新工艺研究 张绪亮1, 刘宗强2,杨建英3，杨建广1，李焌源1，邓自祥1 中南大学 冶金与环境学院，长沙 410083；2.湖南辰州矿业股份有限公司，湖南 沅陵县 419607:3. 江西省环境工程职业学院 摘 要：针对目前铋钼混合矿冶炼中存在选矿流程长，需要消耗大量浮选药剂，分离不彻底等严重弊端，提出了铋钼混合矿直接低温熔炼的方法，铋钼矿经直接低温熔炼得到粗铋，钼以钼酸盐的形式进入浸出液，并可通过“水热法”直接制得氧化钼得以回收。在进行了热力学计算分析的基础上，采用单因素试验法考察了熔盐组成、熔盐量、温度、时间和还原剂用量因素对粗铋品味和铋直收率的影响。获得最优条件为：w（NaCl）/w(NaCl+Na2CO3)=20%，熔炼温度850℃，w(NaCl+Na2CO3)/w(混合矿)=2，熔炼时间1 h，w（活性炭）/w(理论量)=2。在此最优条件下，进行两次综合试验，铋的直收率分别为98.12%和96.59%，纯度分别为96.62%和98.87%。 关键词：低温熔炼，铋钼混合矿，铋冶炼 中图分类号： TF817 文献标志码：A Study on a new process for low-temperature smelting on bismuth-molybdenum ores ZHANG Xuliang1,LIU Zong-qiang2,YANG Jian-ying3,YANG Jian-guang1,LI Jun-yuan1，DENG Zi-xiang1 School of Metallurgy and Environment, Central South University, Changsha 410083: 2. Hunan Chenzhou Mining Corporation Limited, Hunan Ruanling 419607; 3. Jiangxi Environmental Engineering Vocational College, Jiangxi 342000) Abstract: In view of serious shortcoming existing in current bismuth-molybdenum ores floating and smelting such as complex operation in ore-dressing, consume large amounts of floating reagents and bismuth and molybdenum can’t be completely separated, a low-temperature smelting on bismuth-molybdenum ores was proposed. The crude bismuth will be produced after low-temperature smelting, molybdenum became molybdate into the solution. Then the solution can produce molybdenum trioxide by hydrothermal method. On the basis of thermodynamic analysis of this process, effects of molten salt composition, salt amount, smelting temperature, reaction composition and excessive multiples of active carbon on the molten salt smelting of bismuth-molybdenum ores were investigated. The optimum conditions is determined as follows: w (NaCl) / w (NaCl + Na2CO3) = 20%, smelting temperature 850 ℃, w (NaCl + Na2CO3) / w (bismuth-molybdenum ores) = 2, reaction time 1 h, w (activated carbon) / w (theory) = 2. Conducted two comprehensive test under above-mentioned optimum conditions, the direct recovery rate of bismuth is 98