influence of the nature of porphyrin and extraligand on the stability of zinc extracomplexes性质的影响卟啉和extraligand extracomplexes锌的稳定性.pdfVIP

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influence of the nature of porphyrin and extraligand on the stability of zinc extracomplexes性质的影响卟啉和extraligand extracomplexes锌的稳定性.pdf

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influence of the nature of porphyrin and extraligand on the stability of zinc extracomplexes性质的影响卟啉和extraligand extracomplexes锌的稳定性

Molecules 2000, 5, 786-796 molecules ISSN 1420-3049 Influence of the Nature of Porphyrin and Extraligand on the Stability of Zinc Extracomplexes Svetlana V. Zaitzeva*, Sergey A. Zdanovich, Tatiana A. Ageeva, Alexandr S. Ocheretovi and Oleg A. Golubchikov Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya, 1, 153045, Ivanovo, Russian Federation Tel.: +7 0932 378512, E-mail: svz@ihnr.polytech.ivanovo.su Received: 15 March 2000 / Accepted: 29 April 2000 / Published: 9 June 2000 Abstract: The mutual influence of ligands within the structure of Zn-porphyrins on the ther- modynamic stability of the latter was investigated. Keywords: Extracoordination, complex, metalloporphyrins, stability. Introduction The influence of the nature of porphyrin and extraligand on the process of formation of extracom- plexes of zinc porphyrins in o-xylene was studied by a spectrophotometrical titration method and com- puter simulation. For the research the following metalloporphyrins were used: zinc 5,15-(para - butyloxyphenyl)-2,8,12,18-tetramethyl-3,7,13,17-tetraethylporphyrin ZnP(I), zinc 5,15-(para -butyl- oxyphenyl)-2,8,12,18-tetramethyl-3,7,13,17-tetrabutylporhyrin ZnP(II), superimposed zinc porphyrin ZnP(III) and zinc tetraphenylporphyrin ZnP(IV). N-methylimidazole (MeIm), imidazole (Im), pyridine (Py), 3,5-dimethylpyrazole (DMP) and dimethylformamide (DMF) were used as extraligands (L). The strength of Zn-L bonding was noted to be lower within the series of extracomplex stuctures: ZnP(IV) ZnP(I) ZnP(II) ZnP(III). The stability constant (lgK ) in the case of sterically unhindered com-