organic-inorganic hybrid silica material derived from a monosilylated grubbs-hoveyda ruthenium carbene as a recyclable metathesis catalyst有机-无机杂化硅材料来源于monosilylated grubbs-hoveyda钌碳烯作为催化剂可回收的置换作用.pdf

Molecules 2010, 15, 5756-5767; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst Guadalupe Borja 1, Roser Pleixats 1,*, Ramón Alibés 1, Xavier Cattoën 2 and 2 Michel Wong Chi Man 1 Chemistry Department, Universitat Autònoma de Barcelona, Cerdanyola del Vallès, 08193- Barcelona, Spain 2 Institut Charles Gerhardt Montpellier (UMR 5253 CNRS-UM2-ENSCM-UM1), Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l’école normale, 34296 Montpellier cédex 5, France * Author to whom correspondence should be addressed; E-Mail: Roser.Pleixats@uab.es; Tel.: +34-93-581-2067; Fax: +34-93-581-1265. Received: 28 June 2010; in revised form: 10 August 2010 / Accepted: 18 August 2010 / Published: 23 August 2010 Abstract: The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions. Keywords: catalyst immobilization; ring-closing metathesis; organic-inorganic hybrid material; ruthenium alkylidene; sol-gel process