pd(ii)hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins钯(ii)hpmov-catalyzed苯与烯烃的直接氧化偶联反应.pdfVIP

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pd(ii)hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins钯(ii)hpmov-catalyzed苯与烯烃的直接氧化偶联反应.pdf

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pd(ii)hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins钯(ii)hpmov-catalyzed苯与烯烃的直接氧化偶联反应

Molecules 2010, 15, 1487-1500; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Review Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins Yasushi Obora * and Yasutaka Ishii * Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan ∗ Authors to whom correspondence should be addressed; E-Mails: obora@kansai-u.ac.jp (Y.O.); r091001@kansai-u.ac.jp (Y.I.). Received: 15 January 2010; in revised form: 2 February 2010 / Accepted: 8 March 2010 / Published: 9 March 2010 Abstract: The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc) /molybdovanadophosphoric acid (HPMoV) as a key 2 catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation. Keywords: direct coupling; oxidative coupling; arenes; molybdovanadophosphoric acid 1. Introduction The transition-metal-catalyzed arylation of olefins with aryl halides or triflates, which referred to as the Mizoroki-Heck reaction, is an important and a highly versatile C-C bond transformation for the synthesis of arene derivatives [1,2]. However, this existing methodology does not a