perfluoro allyl fluorosulfate (fafs) a versatile building block for new fluoroallylic compounds等烯丙基fluorosulfate(快)为新fluoroallylic化合物多才多艺的构建块.pdf

Molecules 2011, 16, 6512-6540; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Perfluoro Allyl Fluorosulfate (FAFS): A Versatile Building Block for New Fluoroallylic Compounds Ivan Wlassics *, Vito Tortelli, Serena Carella, Cristiano Monzani and Giuseppe Marchionni Solvay Solexis, Viale Lombardia, 20-Bollate, Milan 20021, Italy; E-Mails: vito.tortelli@ (V.T.); serena.carella@ (S.C.); cristiano.monzani@ (C.M.); giuseppe.marchionni@(G.M.) * Author to whom correspondence should be addressed; E-Mail: ivan.wlassics@; Tel.: +39-02 Fax: +39-02 Received: 27 June 2011; in revised form: 22 July 2011 / Accepted: 29 July 2011 / Published: 4 August 2011 Abstract: In this study we will present and discuss both the synthesis of CF =CFCF OSO F (perfluoroallyl fluorosulfate, FAFS), focusing in particular on the 2 2 2 important role of C F /SO ratio, reaction temperature and boron catalyst/SO ratio on 3 6 3 3 FAFS’ yield and selectivity, as well as a wide variety of ionic and radical reactions possible with FAFS. We focused our attention on reactions of FAFS with aliphatic and aromatic alcohols, acyl halides, halides, H O , ketones and radicals whose synthesis and 2 2