phase diagrams of the aqueous two-phase systems of poly(ethylene glycol)sodium polyacrylatesalts水两相系统的相图的聚(乙二醇)钠polyacrylatesalts.pdfVIP
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phase diagrams of the aqueous two-phase systems of poly(ethylene glycol)sodium polyacrylatesalts水两相系统的相图的聚(乙二醇)钠polyacrylatesalts
Polymers 2011, 3, 587-601; doi:10.3390/polym3010587
OPEN ACCESS
polymers
ISSN 2073-4360
/journal/polymers
Article
Phase Diagrams of the Aqueous Two-Phase Systems of
Poly(ethylene glycol)/Sodium Polyacrylate/Salts
Hans-Olof Johansson 1,*, Eloi Feitosa 2 and Adalberto Pessoa Junior 3
1 Department of Biochemistry and Structural Biology, University of Lund, P.O. Box 124, SE-221 00
Lund, Sweden
2 Department of Physics, IBILCE/UNESP, São Paulo State University, Rua Cristovão Colombo,
2265, SP, CEP 15054-000, São Jose do Rio Preto, Brazil; E-Mail: eloifeitosa@
3 Department of Biochemical and Pharmaceutical Technology, University of São Paulo, Av. Prof.
Lineu Prestes, 580—Bloco 16, Cidade Universitaria, CEP 05508-000, São Paulo, Brazil;
E-Mail: pessoajr@usp.br
* Author to whom correspondence should be addressed;
E-Mail: Hans-Olof.Johansson@biochemistry.lu.se; Tel.: +46-46-222 8106; Fax: +46-46-222 4116.
Received: 15 February 2011 / Accepted: 7 March 2011 / Published: 9 March 2011
Abstract: Aqueous two-phase systems consisting of polyethylene glycol (PEG), sodium
polyacrylate (NaPAA), and a salt have been studied. The effects of the polymer size, salt
type (NaCl, Na SO , sodium adipate and sodium azelate) and salt concentrations on the
2 4
position of the binodal curve were investigated. The investigated PEG molecules had a
molar mass of 2,000 to 8,000 g/mol, while that of NaPAA was 8,000 g/mol. Experimental
phase diagrams, and tie lines and calculated phase diagrams, based on Flory-Huggins
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