photocatalytic degradation of methyl orange over metalloporphyrins supported on tio2 degussa p25二氧化钛光催化降解甲基橙的金属支持德固赛p25.pdfVIP
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photocatalytic degradation of methyl orange over metalloporphyrins supported on tio2 degussa p25二氧化钛光催化降解甲基橙的金属支持德固赛p25
Molecules 2012, 17, 1149-1158; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Photocatalytic Degradation of Methyl Orange over
Metalloporphyrins Supported on TiO2 Degussa P25
Xian-Tai Zhou, Hong-Bing Ji * and Xing-Jiao Huang
School of Chemistry and Chemical Engineering, Key Laboratory of Low-Carbon Chemistry Energy
Conservation of Guangdong Province, Sun Yat-sen University, 510275, Guangzhou, China
* Author to whom correspondence should be addressed; E-Mail: jihb@;
Tel.: +86-20-841-13658; Fax: +86-20-841-13654.
Received: 21 November 2011; in revised form: 11 January 2012 / Accepted: 16 January 2012 /
Published: 25 January 2012
Abstract: The photocatalytic activity of meso-tetraphenylporphyrins with different metal
centers (Fe, Co, Mn and Cu) adsorbed on TiO2 (Degussa P25) surface has been
investigated by carrying out the photodegradation of methyl orange (MO) under visible
and ultraviolet light irradiation. The photocatalysts were characterized by X-ray diffraction
(XRD), scanning electron microscopy (SEM), diffuse reflectance UV (DRS-UV-vis) and
infrared spectra. Copper porphyrin-sensitized TiO photocatalyst (CuP-TiO ) showed
2 2
excellent activity for the photodegradation of MO whether under visible or ultraviolet light
irradiation. Natural Bond Orbital (NBO) charges analysis showed that methyl or
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