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plasma depolymerization of chitosan in the presence of hydrogen peroxide等离子体解聚壳聚糖的过氧化氢的存在.pdf

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plasma depolymerization of chitosan in the presence of hydrogen peroxide等离子体解聚壳聚糖的过氧化氢的存在

Int. J. Mol. Sci. 2012, 13, 7788-7797; doi:10.3390/ijm OPEN ACCESS International Journal of Molecular Sciences ISSN 1422-0067 /journal/ijms Article Plasma Depolymerization of Chitosan in the Presence of Hydrogen Peroxide Fengming Ma 1,2, Zhenyu Wang 1,2,*, Haitian Zhao 1 and Shuangqi Tian 1 1 School of Food Science and Engineering, Harbin Institute of Technology, 73 Huanghe Road, Nangang District, Harbin 150090, China; E-Mails: mf163.com (F.M.); zhaoht9999@163.com (H.Z.); tianshuangqi2002@163.com (S.T.) 2 College of Forestry, Northeast Forestry University, 26 Hexing Road Xiangfang District, Harbin 150040, China * Author to whom correspondence should be addressed; E-Mail: wzy219001@; Tel.: +86-451 Fax: +86-451 Received: 23 April 2012; in revised form: 16 June 2012 / Accepted: 18 June 2012 / Published: 21 June 2012 Abstract: The depolymerization of chitosan by plasma in the presence of hydrogen peroxide (H O ) was investigated. The efficiency of the depolymerization was demonstrated 2 2 by means of determination of viscosity-average molecular weight and gel permeation chromatography (GPC). The structure of the depolymerized chitosan was characterized by Fourier-transform infrared spectra (FT-IR), ultraviolet spectra (UV) and X-ray diffraction (XRD). The results showed that chitosan can be effectively degradated by plasma in the presenc